氯溴碘甲烷是一种有机化合物,化学式为CHBrClI。它可由溴二碘甲烷的四氯化碳溶液和五氯化锑的二氯甲烷溶液在0 °C反应得到。[1]
它和其它三卤甲烷一样,可以在低温原位脱质子,得到氯溴碘甲基阴离子。如它和苯基氯化汞在叔丁醇钾的存在下反应,可以得到苯基(氯溴碘甲基)汞。[3]
参考文献
- ^ 1.0 1.1 1.2 Dong Bo Li, Siu-Choon Ng, Igor Novak. Novel synthetic approaches to CHBrFI, CHClFI and CHBrClI. Tetrahedron. 2002-07, 58 (29): 5923–5926 [2021-11-02]. doi:10.1016/S0040-4020(02)00532-X (英语).
- ^ Garino, Mario; Teofili, Ellade. Chlorobromoiodomethane. Gazzetta Chimica Italiana, 1926. 56: 847-852. ISSN 0016-5603
- ^ Charette, A.B.; Aggarwal, V.K.; Aitken, R.A.; Cicchi, S.; Cordero, F. Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 22: Three Carbon-Heteroatom Bonds: Thio-, Seleno-, and Tellurocarboxylic Acids and Derivatives; Imidic Acids and Derivatives; Ortho Acid Derivatives. Thieme. 2014: 662 [2021-11-02]. ISBN 978-3-13-171961-4. (原始内容存档于2021-11-05).