二氟氯碘甲烷

二氟氯碘甲烷
识别
CAS号 420-49-5  checkY
SMILES
 
  • ClC(F)(F)I
性质
化学式 CClF2I
摩尔质量 212.36 g·mol−1
沸点 33 °C（306 K）[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

二氟氯碘甲烷是一种有机化合物，化学式为CClF2I。它可由二氟氯乙酸甲酯、LiCl/HMPA和碘或一溴化碘在90~95 °C反应，或二氟氯乙酸银和碘在120~260 °C反应得到：[2]

CClF2COOAg + I2 → CClF2I + CO2 + AgBr

六氟乙烷或三氟氯甲烷和碘的电感耦合等离子体（12 MHz）反应也能得到二氟氯碘甲烷。[3]

参考文献

  1. ^ Haszeldine, Robert N. Polyhalomethanes. 1955 US 2716668.
  2. ^ Katritzky, A.R.; Gilchrist, T.L.; Meth-Cohn, O.; Rees, C.W. Comprehensive Organic Functional Group Transformations. Comprehensive Organic Functional Group Transformations. Elsevier Science. 1995: 224 [2021-10-26]. ISBN 978-0-08-042704-1. （原始内容存档于2021-10-27）.  |issue=被忽略 (帮助) （页面存档备份，存于互联网档案馆）
  3. ^ chmeisser, Martin; Heuser, Wilfried; Danzmann, Erich. Preparation of trifluoroiodomethane, bromotrifluoromethane, and trifluoronitrosomethane by chemical plasma. Zeitschrift fuer Anorganische und Allgemeine Chemie, 1975. 418 (2): 109-115. ISSN 0044-2313.

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