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Primera División 1980-81 var den 50. sesongen i spansk toppfotball siden den ble innført. Sesongen startet 6. september 1980 og ble avsluttet 26. april 1981. Quini fra FC Barcelona ble toppscorer med 20 ligamål.Året før ble han også toppscorer, men da for Sporting Gijon. Real Sociedad vant sin første ligatittel denne sesongen.

Ligatabell

Plass	Klubb	K	V	U	T	MF-MM	P
1	Real Sociedad	34	19	7	8	52-29	45
2	Real Madrid CF	34	20	5	9	66-37	45
3	Valencia CF	34	17	8	9	59-41	42
4	Atlético de Madrid	34	16	10	8	46-39	42
5	FC Barcelona	34	18	5	11	66-41	41
6	Real Betis Balompié	34	17	6	11	55-38	40
7	Sporting de Gijón	34	14	10	10	58-40	38
8	Sevilla FC	34	14	9	11	34-42	37
9	Athletic Club	34	14	7	13	64-53	35
10	RCD Espanyol	34	14	6	14	37-42	34
11	CA Osasuna	34	12	8	14	35-46	32
12	Real Valladolid CF	34	9	13	12	40-46	31
13	Hércules CF	34	10	10	14	42-48	30
14	Real Zaragoza	34	9	11	14	31-44	29
15	UD Las Palmas	34	12	4	18	47-61	28
16	Real Murcia CF	34	8	7	19	35-49	23
17	UD Salamanca	34	7	7	20	32-67	21
18	AD Almería	34	6	7	21	30-66	19

K=kamper spilt, V= vunnet, U= uavgjort, T= tap, MF-MM= mål for-mål mot, P = Poeng

Resultater

	ALM	ATH	ATM	BAR	BET	ESP	HÉR	LPA	MUR	OSA	RMA	RSO	SAL	SEV	SPG	VAL	VLD	ZAR
AD Almería		1-1	2-1	2-5	0-2	2-0	0-3	0-1	0-0	1-1	1-2	3-2	3-2	0-0	1-1	1-0	1-1	3-1
Athletic Bilbao	5-1		3-1	4-1	2-0	1-2	5-3	1-3	3-0	1-1	1-1	0-2	6-1	3-0	1-1	4-0	4-1	0-1
Atlético Madrid	2-1	2-1		1-0	0-4	1-0	1-0	2-2	2-1	0-0	3-1	2-0	1-1	2-0	0-0	3-1	5-2	1-2
FC Barcelona	6-0	0-1	4-2		1-3	3-1	6-0	1-0	1-0	6-0	2-1	2-0	3-0	3-1	3-1	0-3	2-1	0-0
Betis	2-0	2-0	0-1	1-1		1-2	2-0	4-1	1-0	1-1	1-1	1-0	5-0	2-0	2-0	1-1	2-2	2-0
RCD Español	1-0	1-0	2-0	1-0	1-2		2-1	3-1	2-1	0-0	2-1	0-0	2-1	2-2	1-0	1-2	0-0	1-1
Hércules CF	1-0	1-2	1-2	0-1	0-1	2-0		2-3	1-0	0-0	1-2	2-0	3-2	5-1	1-1	1-1	1-1	1-1
UD Las Palmas	3-0	1-3	1-1	1-4	2-4	2-0	1-1		1-2	2-0	1-0	0-3	1-1	1-2	3-1	1-4	0-2	3-0
Murcia	2-1	5-4	0-2	1-2	2-0	1-1	2-2	1-2		1-0	1-1	0-2	1-1	0-0	2-1	0-2	0-0	0-1
Osasuna	2-1	2-0	0-0	1-0	1-2	1-0	1-2	1-0	3-1		1-2	0-3	1-1	2-1	3-0	2-0	2-0	1-0
Real Madrid	4-0	7-1	2-0	3-0	4-2	1-2	3-0	3-0	4-0	3-1		1-0	2-0	3-2	1-0	2-1	1-1	2-0
Real Sociedad	3-1	4-1	2-2	2-0	2-2	2-1	1-1	2-0	1-0	2-1	3-1		1-0	3-0	1-2	2-1	1-0	1-0
UD Salamanca	3-2	2-1	1-1	2-1	2-0	3-2	0-1	0-2	0-3	1-2	1-3	0-2		0-0	2-2	0-1	2-1	3-1
Sevilla FC	1-0	2-0	1-1	1-1	2-1	2-0	0-0	3-2	1-0	1-0	2-0	0-0	1-0		3-2	1-0	1-0	0-0
Sporting de Gijón	5-2	1-1	3-0	2-1	2-0	0-1	3-1	2-1	2-0	5-1	4-0	2-2	4-0	3-0		0-0	4-1	1-1
Valencia CF	3-1	0-0	1-1	3-3	3-1	3-1	0-2	3-1	3-2	4-1	2-1	3-2	3-0	2-0	3-1		2-2	3-0
Valladolid	0-0	0-0	0-2	1-1	2-1	3-1	2-1	3-1	1-0	2-1	1-3	0-0	3-0	2-3	1-2	2-0		1-1
Zaragoza	1-0	2-3	0-1	1-2	2-0	2-1	1-1	2-3	1-6	3-1	0-0	0-1	2-0	2-0	0-0	1-1	1-1