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偶氮二(2-甲基己腈)

偶氮二(2-甲基己腈)
英文名 2,2'-azobis(2-methylhexanenitrile)
别名 AIHN、AVBN、ABVN
识别
CAS号 15545-95-6  checkY
性质
化学式 C14H24N4
摩尔质量 248.37 g·mol−1
密度 0.92 ± 0.1 g·cm−3(20 °C)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

偶氮二(2-甲基己腈)是一种有机化合物,化学式为C14H24N4。它可由甲基戊基甲酮、联氨氰化钠反应,得到N,N′-取代的有机肼,再于乙醇中对肼进行氧化,得到偶氮二(2-甲基己腈)。它可在乙醚中进行重结晶[2]它受热可以分解。[3]

参考文献

  1. ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (1994-2019 ACD/Labs). Retrieved from SciFinder. [2019-10-29]
  2. ^ C. G. Overberger, M. T. O'Shaughnessy, Harold. Shalit. The Preparation of Some Aliphatic Azo Nitriles and their Decomposition in Solution. Journal of the American Chemical Society. 1949-08, 71 (8): 2661–2666 [2019-10-29]. ISSN 0002-7863. doi:10.1021/ja01176a018 (英语). 
  3. ^ Kovtun, G. A.; Lysenko, D. L.; Livanskaya, G. N. Steric effect on the efficiency of free-radical formation from azobisnitriles(俄文). Ukrainskii Khimicheskii Zhurnal (Russian Edition), 1990. 56 (6): 636-638. ISSN: 0041-6045.

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