1,4-环庚二烯
1,4-环庚二烯
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IUPAC名 Cyclohepta-1,4-diene
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识别
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缩写
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1,4-CHDN
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CAS号
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7161-35-5 Y
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PubChem
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138950
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ChemSpider
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122548
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SMILES
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InChI
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- 1S/C7H10/c1-2-4-6-7-5-3-1/h1-2,5,7H,3-4,6H2
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UN编号
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3295
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MeSH
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1,4-cycloheptadiene
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性质
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化学式
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C7H10
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摩尔质量
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94.15 g·mol−1
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外观
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无色液体
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密度
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0.84 g cm−3
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沸点
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112-116 °C[1]
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折光度n D
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1.48
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危险性
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GHS危险性符号
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GHS提示词
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危险
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H-术语
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H225, H340, H350, H373
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P-术语
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P201, P210, P308+313
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NFPA 704
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若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。
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1,4-环庚二烯(英語:1,4-Cycloheptadiene,或称为环庚-1,4-二烯,英語:Cyclohepta-1,4-diene)是一种环烯烃,分子式C7H10,高度可燃,常温常压下为无色澄清液体。它在环庚三烯的还原反应中以副产物生成。[2]它和钯形成的配合物是黄色的。[3]
参考文献
- ^ Xiaodong Gu, Wujuan Zhang, Robert G. Salomon. Fe2+ Catalyzes Vitamin E-Induced Fragmentation of Hydroperoxy and Hydroxy Endoperoxides That Generates γ-Hydroxy Alkenals. Journal of the American Chemical Society. 2007-05-01, 129 (19): 6088–6089 [2022-03-24]. ISSN 0002-7863. doi:10.1021/ja0689785.
- ^ Tae Bo Sim, Nung Min Yoon. Reducing Characteristics of Borohydride Exchange Resin–CuSO4 in Methanol. Bulletin of the Chemical Society of Japan. 1997-05-01, 70 (5): 1101–1107 [2022-03-24]. ISSN 0009-2673. doi:10.1246/bcsj.70.1101.
- ^ Rettig, Michael F.; Wing, Richard M. X-ray crystallographic, chemical, and spectroscopic studies of the palladium dichloride complexes of cyclonona-1,5-diene, cycloocta-1,5-diene, cycloocta-1,4-diene, and cyclohepta-1,4-diene. Journal of the American Chemical Society. June 1981, 103 (11): 2980–2986. doi:10.1021/ja00401a012.
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