Трисульфид титана

Трисульфид титана
Общие
Систематическое
наименование
Трисульфид титана
Традиционные названия Сернистый титан
Хим. формула TiS3
Физические свойства
Состояние кристаллы
Молярная масса 144,06 г/моль
Плотность 3,1 г/см³
Термические свойства
Температура
 • разложения 632 °C
Классификация
Рег. номер CAS 12423-80-2
Приведены данные для стандартных условий (25 °C, 100 кПа), если не указано иное.

Трисульфид титана — бинарное неорганическое соединение титана и серы с формулой TiS3, кристаллы.

Получение

  • Нагревание стехиометрической смеси чистых веществ:

Физические свойства

Трисульфид титана образует кристаллы моноклинной сингонии, пространственная группа P 21/m, параметры ячейки a = 0,4973÷0,501 нм, b = 0,338÷0,3433 нм, c = 0,8714÷0,888 нм, β = 97,17÷97,74°, Z = 2, структура типа триселенида циркония ZrSe3 [1][2][3].

Соединение образуется по перитектической реакции при температуре 632°C.

Применение

Примечания

  1. Диаграммы состояния двойных металлических систем / Под ред. Н. П. Лякишева. — М.: Машиностроение, 2000. — Т. 3 Книга 2. — 448 с. — ISBN 5-217-02932-3.
  2. B. Predel. S-Ti (Sulfur-Titanium) // Landolt-Börnstein - Group IV Physical Chemistry. — 1998. — Т. 5J. — С. 1-4. — doi:10.1007/10551312_2665.
  3. J. L. Murray. The S−Ti (Sulfur-Titanium) system // Bulletin of Alloy Phase Diagrams. — 1986. — Т. 7, № 2. — С. 156-163. — doi:10.1007/BF02881555.
  4. Alexey Lipatov, Peter M. Wilson, Mikhail Shekhirev, Jacob D. Teeter, Ross Netusila, Alexander Sinitskii. Few-layered titanium trisulfide (TiS3) field-effect transistors // Nanoscale. — 2015. — Т. 7. — С. 12291-12296. — doi:10.1039/C5NR01895A.


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