Borocookeite

Borocookeite
Classificazione Strunz (ed. 10)9.EC.55[1]
Formula chimica
  • LiAl4(Si3B)O10(OH)8[2]
  • Li1,3Al3,8[((OH)0,75F0,25)8(B0,75Al0,25)Si3O10][3]
Proprietà cristallografiche
Sistema cristallinomonoclino[4]
Parametri di cellaa = 5,110 Å, b = 8,856 Å, c = 14,080 Å, β = 96,93°, Z = 2[5]
Gruppo puntuale2/m[6]
Gruppo spazialeC2/m[6]
Proprietà fisiche
Densità misurata2,62(1)[4] g/cm³
Densità calcolata2,69(1)[4] g/cm³
Durezza (Mohs)3[5]
Sfaldaturaperfetta lungo {001}[6]
Coloreincolore, grigio chiaro con una sfumatura rosata o gialla[7]
Lucentezzaoleosa[4]
Opacitàtraslucida[4]
Strisciobianco,[3] grigio rosato chiaro[4]
Diffusionerara
Si invita a seguire lo schema di Modello di voce – Minerale

La borocookeite (simbolo IMA: Bckt[8]) è un minerale del gruppo della clorite appartenente alla classe minerale dei "silicati e germanati" con composizione chimica LiAl4(Si3B)O10(OH)8.[2]

Strutturalmente appartiene ai fillosilicati.

Etimologia e storia

Il nome deriva dalla composizione chimica, simile alla cookeite (LiAl4(Si3Al)O10(OH)8) ma dove un atomo di alluminio è sostituito da un atomo di boro.[4]

Classificazione

La nona edizione della sistematica minerale di Strunz, valida dal 2001 e aggiornata dall'IMA fino al 2009,[9] classifica la borocookeite nella classe "9. Silicati (germanati)" e lì nella sottoclasse "9.E Fillosilicati"; questa è ulteriormente suddivisa in base alla struttura cristallina, in modo che il minerale possa essere trovato nella suddivisione "9.EC Fillosilicati con fogli di mica, composti di reti di tetraedri e ottaedri", dove può essere trovato insieme a baileycloro, franklinfurnaceite, glagolevite, nimite, chamosite, clinocloro, cookeite, donbassite, gonyerite, pennantite e sudoite con le quali forma il sistema nº 9.EC.55.[3]

Tale classificazione viene mantenuta anche nell'edizione successiva, proseguita dal database "mindat.org" e chiamata Classificazione Strunz-mindat.[1]

Anche la sistematica dei minerali secondo Dana classifica la borocookeite nella classe dei "silicati e germanati" e lì nella sottoclasse dei "minerali fillosilicati"; qui è insieme a baileycloro, chamosite, cookeite, donbassite, clinocloro, nimite, ortochamosite, pennantite, sudoite con le quali forma il sistema n. 71.04.01 all'interno della sottosezione "fillosilicati: strati di anelli a sei membri, alternatamente 1:1, 2:1 e ottaedrici".[3]

Abito cristallino

La borocookeite cristallizza nel sistema monoclino nel gruppo spaziale C2/m (gruppo nº 12) con i parametri reticolari a = 5,110 Å, b = 8,856 Å, c = 14,080 Å, β = 96,93°, oltre a 2 unità di formula per cella unitaria.[5]

Origine e giacitura

La borocookeite si presenta come aggregati densi e massicci o in croste sottili e rivestimenti simili a cristalli di neve con dimensioni fino a 0,15 mm. La si trova associata a elbaite, lepidolite, danburite, boromuscovite, laumontite, quarzo e albite.[7]

Essendo un minerale molto raro, la borocookeite è stata trovata solo in pochissimi: nel territorio della Transbajkalia nelle vene di pegmatite "Mokhovaya" e "Sosedka" (quest'ultima è la località tipo) in Russia e negli Stati federati del Brasile Minas Gerais e Rio Grande do Norte.[10]

Note

  1. ^ a b (EN) Strunz-mindat (2024) Classification - Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets, su mindat.org. URL consultato il 26 novembre 2024.
  2. ^ a b (EN) Malcolm Back et al., The New IMA List of Minerals – A Work in Progress – Updated: November 2024 (PDF), su cnmnc.units.it, IMA/CNMNC, Marco Pasero, novembre 2024. URL consultato il 25 novembre 2024.
  3. ^ a b c d (EN) Borocookeite, su mineralienatlas.de. URL consultato il 26 novembre 2024.
  4. ^ a b c d e f g (EN) Borocookeite, su mindat.org. URL consultato il 26 novembre 2024.
  5. ^ a b c (EN) Victor Y. Zagorsky, Igor S. Peretyazhko, Anatoliy N. Sapozhnikov, Anatoliy P. Zhukhlistov e Boris B. Zvyagin, Borocookeite, a new member of the chlorite group from the Malkhan gem tourmaline deposit, Central Transbaikalia, Russia, in American Mineralogist, vol. 88, n. 5, 2003, pp. 830-836. URL consultato il 26 novembre 2024.
  6. ^ a b c (EN) Borocookeite Mineral Data, su webmineral.com. URL consultato il 26 novembre 2024.
  7. ^ a b (EN) Borocookeite (PDF), in Handbook of Mineralogy. URL consultato il 26 novembre 2024.
  8. ^ (EN) Laurence N. Warr, IMA–CNMNC approved mineral symbols (PDF), in Mineralogical Magazine, vol. 85, 2021, pp. 291–320, DOI:10.1180/mgm.2021.43. URL consultato il 26 novembre 2024.
  9. ^ (EN) Ernest Henry Nickel e Monte C. Nichols, IMA/CNMNC List of Minerals 2009 (PDF), su cnmnc.units.it, IMA/CNMNC, gennaio 2009. URL consultato il 25 novembre 2024 (archiviato dall'url originale il 29 luglio 2024).
  10. ^ (EN) Localities for Borocookeite, su mindat.org. URL consultato il 26 novembre 2024.

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