It occurs naturally as the mineralsylvite, which is named after salt's historical designations sal degistivum Sylvii and sal febrifugum Sylvii,[9] and in combination with sodium chloride as sylvinite.[10]
Uses
Fertilizer
The majority of the potassium chloride produced is used for making fertilizer, called potash, since the growth of many plants is limited by potassium availability. Potassium chloride sold as fertilizer is known as muriate of potash. The vast majority of potash fertilizer worldwide is sold as muriate of potash.[citation needed]
Potassium chloride can be used as a salt substitute for food, but due to its weak, bitter, unsalty flavor, it is often mixed with ordinary table salt (sodium chloride) to improve the taste, to form low sodium salt. The addition of 1 ppm of thaumatin considerably reduces this bitterness.[12] Complaints of bitterness or a chemical or metallic taste are also reported with potassium chloride used in food.[13]
Execution
In the United States, potassium chloride is used as the final drug in the three injection sequence of lethal injection as a form of capital punishment. It induces cardiac arrest, ultimately killing the inmate.[14]
Glass manufacturers use granular potash as a flux, lowering the temperature at which a mixture melts. Because potash imparts excellent clarity to glass, it is commonly used in eyeglasses, glassware, televisions, and computer monitors.
Because natural potassium contains a tiny amount of the isotope potassium-40, potassium chloride is used as a beta radiation source to calibrate radiation monitoring equipment. It also emits a relatively low level of 511 keV gamma rays from positron annihilation, which can be used to calibrate medical scanners.
Potassium chloride is used in some de-icing products designed to be safer for pets and plants, though these are inferior in melting quality to calcium chloride. It is also used in various brands of bottled water.
Potassium chloride was once used as a fire extinguishing agent, and in portable and wheeled fire extinguishers. Known as Super-K dry chemical, it was more effective than sodium bicarbonate-based dry chemicals and was compatible with protein foam. This agent fell out of favor with the introduction of potassium bicarbonate (Purple-K) dry chemical in the late 1960s, which was much less corrosive, as well as more effective. It is rated for B and C fires.
Potassium chloride is also an optical crystal with a wide transmission range from 210 nm to 20 μm. While cheap, KCl crystals are hygroscopic. This limits its application to protected environments or short-term uses such as prototyping. Exposed to free air, KCl optics will "rot". Whereas KCl components were formerly used for infraredoptics, it has been entirely replaced by much tougher crystals such as zinc selenide.
The typical amounts of potassium chloride found in the diet appear to be generally safe.[15] In larger quantities, however, potassium chloride is toxic. The LD50 of orally ingested potassium chloride is approximately 2.5 g/kg, or 190 grams (6.7 oz) for a body mass of 75 kilograms (165 lb). In comparison, the LD50 of sodium chloride (table salt) is 3.75 g/kg.
Intravenously, the LD50 of potassium chloride is far smaller, at about 57.2 mg/kg to 66.7 mg/kg; this is found by dividing the lethal concentration of positive potassium ions (about 30 to 35 mg/kg)[16] by the proportion by mass of potassium ions in potassium chloride (about 0.52445 mg K+/mg KCl).[17]
Solutions of KCl are common standards, for example for calibration of the electrical conductivity of (ionic) solutions, since KCl solutions are stable, allowing for reproducible measurements. In aqueous solution, it is essentially fully ionized into solvated K+ and Cl− ions.
Redox and the conversion to potassium metal
Although potassium is more electropositive than sodium, KCl can be reduced to the metal by reaction with metallic sodium at 850 °C because the more volatile potassium can be removed by distillation (see Le Chatelier's principle):
This method is the main method for producing metallic potassium. Electrolysis (used for sodium) fails because of the high solubility of potassium in molten KCl.[10]
Other potassium chloride stoichiometries
Potassium chlorides with formulas other than KCl have been predicted to become stable under pressures of 20 GPa or more.[19] Among these, two phases of KCl3 were synthesized and characterized. At 20-40 GPa, a trigonal structure containing K+ and Cl3− is obtained; above 40 GPa this gives way to a phase isostructural with the intermetallic compound Cr3Si.
Physical properties
Under ambient conditions the crystal structure of potassium chloride is like that of NaCl. It adopts a face-centered cubic structure known as the B1 phase with a lattice constant of roughly 6.3 Å. Crystals cleave easily in three directions. Other polymorphic and hydrated phases are adopted at high pressures.[20]
Some other properties are
Transmission range: 210 nm to 20 μm
Transmittivity = 92% at 450 nm and rises linearly to 94% at 16 μm
Refractive index = 1.456 at 10 μm
Reflection loss = 6.8% at 10 μm (two surfaces)
dN/dT (expansion coefficient)= −33.2×10−6/°C
dL/dT (refractive index gradient)= 40×10−6/°C
Thermal conductivity = 0.036 W/(cm·K)
Damage threshold (Newman and Novak): 4 GW/cm2 or 2 J/cm2 (0.5 or 1 ns pulse rate); 4.2 J/cm2 (1.7 ns pulse rate Kovalev and Faizullov)
As with other compounds containing potassium, KCl in powdered form gives a lilac flame.
The vast majority of potassium chloride is produced as agricultural and industrial grade potash in Saskatchewan, Canada, as well as Russia and Belarus. Saskatchewan alone accounted for over 25% of the world's potash production in 2017.[21]
Laboratory methods
Potassium chloride is inexpensively available and is rarely prepared intentionally in the laboratory. It can be generated by treating potassium hydroxide (or other potassium bases) with hydrochloric acid:
This conversion is an acid-base neutralization reaction. The resulting salt can then be purified by recrystallization. Another method would be to allow potassium to burn in the presence of chlorine gas, also a very exothermic reaction:
^Rayner-Canham G (22 December 2013). Descriptive inorganic chemistry. Overton, Tina (Sixth ed.). New York, NY. ISBN978-1-4641-2557-7. OCLC882867766.{{cite book}}: CS1 maint: location missing publisher (link)
^World Health Organization (2019). World Health Organization model list of essential medicines: 21st list 2019. Geneva: World Health Organization. hdl:10665/325771. WHO/MVP/EMP/IAU/2019.06. License: CC BY-NC-SA 3.0 IGO.
^Sinopoli DA, Lawless HT (September 2012). "Taste properties of potassium chloride alone and in mixtures with sodium chloride using a check-all-that-apply method". Journal of Food Science. 77 (9): S319–S322. doi:10.1111/j.1750-3841.2012.02862.x. PMID22901084.
^Bhatkhande CY, Joglekar VD (1977-01-01). "Fatal poisoning by potassium in human and rabbit". Forensic Science. 9 (1): 33–36. doi:10.1016/0300-9432(77)90062-0. PMID838413.