Lithium hexafluoroantimonate

Lithium hexafluoroantimonate

Names
IUPAC name lithium;hexafluoroantimony(1-)
Other names Lithium hexafluoroantimonate(V)
Identifiers
CAS Number	18424-17-4
3D model (JSmol)	Interactive image
ChemSpider	16700586
ECHA InfoCard	100.196.093
EC Number	670-363-3
PubChem CID	16700586
CompTox Dashboard (EPA)	DTXSID00587189
InChI InChI=1S/6FH.Li.Sb/h6*1H;;/q;;;;;;+1;+5/p-6 Key: YVBBFYDVCPCHHG-UHFFFAOYSA-H
SMILES [Li+].F[Sb-](F)(F)(F)(F)F
Properties
Chemical formula	NaSbF6
Appearance	White to off-white powder
Solubility in water	soluble
Hazards
GHS labelling:
Pictograms
Signal word	Warning
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Lithium hexafluoroantimonate is an inorganic chemical compound with the chemical formula LiSbF₆.^[1][2][3]

Physical properties

The compound crystallizes in the rhombohedral space group R3 with the lattice constants a = 5.43 Å, α = 56° 58', Z = 1. The structure corresponds to that of rhombohedral distorted NaSbF₆ type.^[4][5]

References

1. "Lithium hexafluoroantimonate(V)". Sigma Aldrich. Retrieved 1 July 2024.
2. Haynes, William M. (9 June 2015). CRC Handbook of Chemistry and Physics, 96th Edition. CRC Press. p. 4-72. ISBN 978-1-4822-6097-7. Retrieved 1 July 2024.
3. Manthiram, Arumugam (March 2009). Rechargeable Lithium and Lithium Ion Batteries. The Electrochemical Society. p. 157. ISBN 978-1-56677-704-9. Retrieved 1 July 2024.
4. Burns, J. H. (10 November 1962). "The crystal structure of lithium fluoroantimonate(V)". Acta Crystallographica. 15 (11): 1098–1101. doi:10.1107/S0365110X62002935. ISSN 0365-110X. Retrieved 1 July 2024.
5. Donnay, Joseph Désiré Hubert (1978). Crystal Data: Inorganic compounds 1967-1969. National Bureau of Standards. p. H/R-188. Retrieved 1 July 2024.