二甲锗基硫是一种无机化合物,化学式为H3GeSGeH3,其分子中Ge-S键键长为2.209 Å,Ge-S-Ge键角为98.9°。[2]它可由硫化锂和溴代甲锗烷在二甲醚中反应得到。[3]它和硫化氢反应得到巯基甲锗烷。[4]
- (GeH3)2S + H2S ⇌ 2GeH3SH
参考文献
- ^ 1.0 1.1 Norbert W. Mitzel, Udo Losehand. Dimethyl-, Disilyl- and Digermylsulfide: Different Intermolecular Contacts in the Solid State. Zeitschrift für Naturforschung B. 2004-06-01, 59 (6): 635–638 [2021-06-10]. ISSN 1865-7117. doi:10.1515/znb-2004-0603.
- ^ C. Glidewell, D. W. H. Rankin, A. G. Robiette, G. M. Sheldrick, B. Beagley, S. Cradock. Molecular structures of digermyl ether and digermyl sulphide in the gas phase, studied by electron diffraction. Journal of the Chemical Society A: Inorganic, Physical, Theoretical. 1970: 315 [2021-06-10]. ISSN 0022-4944. doi:10.1039/j19700000315 (英语).
- ^ D. W. H. Rankin, J. M. Bellama, L. A. Harmon. George W. Parshall , 编. Digermyl Sulfide ( Digermthiane ). Hoboken, NJ, USA: John Wiley & Sons, Inc. 2007-01-05: 182–184 [2021-06-10]. ISBN 9780470132463. doi:10.1002/9780470132463.ch40.
- ^ C. Glidewell, D. W. H. Rankin, G. M. Sheldrick. N.M.R. studies of mixed group 4/group 6 hydrides. Transactions of the Faraday Society. 1969, 65: 1409 [2021-06-10]. ISSN 0014-7672. doi:10.1039/tf9696501409 (英语).