疊氮化銫

疊氮化銫是一種無機化合物，由銫和氮構成，屬於疊氮酸鹽、疊氮化合物，其化學式為CsN₃。晶體結構為四方結構，和同族疊氮化合物相似^[5]。在加熱或紫外線照射時，它會分解成氮氣和金屬銫。^[6]^[7]要制備疊氮化銫可將和碳酸銫和疊氮酸的中和反應製備；或胺基銫與一氧化二氮反應而制得；或碳酸銫和疊氮化鈉的複分解反應製備，反應式如下:

Cs₂CO₃ + 2HN₃ → 2CsN₃ + H₂CO₃

CsNH₂ + N₂O → CsN₃ + H₂O

Cs₂CO₃ + 2NaN₃ → 2CsN₃ + Na₂CO₃

參考文獻

^ ^1.0 ^1.1 Dale L. Perry; Sidney L. Phillips. Handbook of inorganic compounds. CRC Press. 1995: 301. ISBN 0849386713.
^ 来源：Sigma-Aldrich Co., product no. 510181 .
^ Georg Brauer, Handbuch der Präparativen Anorganischen Chemie, Band I, Seite 458. 1975,
ISBN 3-432-02328-6
（德文）
^ Dale L. Perry, Sidney L. Phillips: Handbook of Inorganic Compounds, 2nd ed.. CRC Press, 2010, ISBN 978-1-4398-1461-1
^ ^5.0 ^5.1 Khilji, M. Y.; Sherman, W. F.; Wilkinson, G. R. Variable temperature and pressure Raman spectra of potassium azide KN3. Journal of Raman Spectroscopy (Wiley-Blackwell). 1982, 12 (3): 300–303. ISSN 0377-0486. doi:10.1002/jrs.1250120319.
^ Tompkins, F. C.; Young, D. A. The Photochemical and Thermal Formation of Colour Centres in Potassium Azide Crystals. Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences. 1982, 236 (1204): 10–23.
^ Pradyot Patnaik. Handbook of inorganic chemicals. McGraw-Hill Professional. 2003: 734. ISBN 0070494398.
^ Pringle, G. E.; Noakes, D. E. The crystal structures of lithium, sodium and strontium azides. Acta Cryst. February 1968,. B24 (2): 262–269. doi:10.1107/S0567740868002062.