氢化亚铜

氢化亚铜
	IUPAC名; 氢化亚铜
识别
CAS号	13517-00-5
PubChem	3335333
ChemSpider	2582262
SMILES	[CuH];
性质
化学式	HCu
摩尔质量	64.55 g·mol−1
熔点	100 °C（212 °F；373 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

氢化亚铜（化学式：CuH）是铜的二元氢化物。Cu-H键很弱因此这种化合物是不稳定的。^[2]^[3]硫酸铜与次磷酸钠在少量硫酸存在的条件下反应得到这种红色沉淀。它受热就分解为金属铜和氢气。X射线衍射实验已经测定了它的晶体结构。^[4]它与三苯基膦的加合物是有机化学中的斯瑞克试剂（英语：Stryker's reagent）。

参考资料

^ Fitzsimons, Nuala P.; Jones, William; Herley, Patrick J. Studies of copper hydride. Part 1.—Synthesis and solid-state stability. Journal of the Chemical Society, Faraday Transactions. 1 January 1995, 91 (4): 713–718. doi:10.1039/FT9959100713.
^ Hydrides of the Main-Group Metals: New Variations on an Old Theme Simon Aldridge , Anthony J. Downs Chem. Rev., 2001, 101 (11), pp 3305–3366 doi:10.1021/cr960151d
^ Laboratory Methods of Inorganic Chemistry Wilhelm Biltz Heinrich
^ The crystal structure of copper hydride J. A. Goedkoop and A. F. Andresen Acta Cryst. (1955). 8, 118-119 doi:10.1107/S0365110X55000480

[Fitzsimons1995-1] Fitzsimons, Nuala P.; Jones, William; Herley, Patrick J. Studies of copper hydride. Part 1.—Synthesis and solid-state stability. Journal of the Chemical Society, Faraday Transactions. 1 January 1995, 91 (4): 713–718. doi:10.1039/FT9959100713.

[2] Hydrides of the Main-Group Metals: New Variations on an Old Theme Simon Aldridge , Anthony J. Downs Chem. Rev., 2001, 101 (11), pp 3305–3366 doi:10.1021/cr960151d

[3] Laboratory Methods of Inorganic Chemistry Wilhelm Biltz Heinrich

[4] The crystal structure of copper hydride J. A. Goedkoop and A. F. Andresen Acta Cryst. (1955). 8, 118-119 doi:10.1107/S0365110X55000480

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氢化亚铜

参考资料

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