Реакция Реформатского

Реакция Реформатского — органическая реакция, конденсация альдегидов или кетонов (1) с эфирами α-галогенкарбоновых кислот (2), происходящая в апротонном растворителе под действием порошка цинка, и приводящая к образованию эфиров β-гидроксикарбоновых кислот (3).

В качестве интермедиата в реакции образуется цинковый енолят, который иногда называют «енолятом Реформатского».

Реакции Реформатского были посвящены несколько обзорных публикаций.[1][2]

Примечания

  1. Shriner, R. L. Org. React. 1942, 1, 1. (Review)
  2. Rathke, M. W. Org. React. 1975, 22, 423. (Review)

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