Note: Flags indicate national team as defined under FIFA eligibility rules; some limited exceptions apply. Players may hold more than one non-FIFA nationality.
CFR Cluj, as Liga I winners in the previous season, played against Universitatea Craiova in the 2021 Supercupa României, who themselves won the Cupa României.
Source: Soccerway, FRF(in Romanian), LPF(in Romanian) Rules for classification: 1) Points; 2) Points without rounding; 3) Head-to-head points; 4) Head-to-head goal difference; 5) Head-to-head goals scored; 6) Goal difference; 7) Goals scored; 8) Play-off (only if needed to decide champion or teams for UEFA competitions). (Note: only criteria 6 and 7 are applied to establish the classification during the competition.)[4] (C) Champions; (O) Play-off winners