Walter Kohn (German pronunciation:[ˈvaltɐˈkoːn]; March 9, 1923 – April 19, 2016)[3] was an Austrian-American theoretical physicist and theoretical chemist.
He was awarded, with John Pople, the Nobel Prize in Chemistry in 1998.[4] The award recognized their contributions to the understandings of the electronic properties of materials. In particular, Kohn played the leading role in the development of density functional theory, which made it possible to calculate quantum mechanical electronic structure by equations involving the electronic density (rather than the many-body wavefunction). This computational simplification led to more accurate calculations on complex systems as well as many new insights, and it has become an essential tool for materials science, condensed-phase physics, and the chemical physics of atoms and molecules.[5]
Early years in Canada
Kohn arrived in England as part of the Kindertransport rescue operation immediately after the annexation of Austria by Hitler.[6] He was from a Jewish family, and has written, "My feelings towards Austria, my native land, are – and will remain – very painful. They are dominated by my vivid recollections of 1 1/2 years as a Jewish boy under the Nazi regime, and by the subsequent murder of my parents, Salomon and Gittel Kohn, of other relatives and several teachers, during the Holocaust. ... I want to mention that I have a strong Jewish identity and – over the years – have been involved in several Jewish projects, such as the establishment of a strong program of Judaic Studies at the University of California in San Diego.".[7][5] Kohn also has identified as Deist.[8]
Because he was an Austrian national, he was transferred to Canada in July 1940 after the outbreak of World War II. As a 17-year-old, Kohn traveled as part of a British convoy moving through U-boat-infested waters to Quebec City in Canada; and from there, by train, to a camp in Trois-Rivières. He was at first held in detention in a camp near Sherbrooke, Quebec. This camp, as well as others, provided a small number of educational facilities that Kohn used to the fullest, and he finally succeeded in entering the University of Toronto. As a German national, the future Nobel Laureate in Chemistry was not allowed to enter the chemistry building, and so he opted for physics and mathematics.[7]
Scientific career
Kohn received a war-time bachelor's degree in applied mathematics at the end of his one-year army service, having completed only 2½ out of the 4-year undergraduate program, from the University of Toronto in 1945; he was awarded an M.A. degree in applied mathematics by Toronto in 1946. Kohn was awarded a Ph.D. degree in physics by Harvard University in 1948, where he worked under Julian Schwinger on the three-body scattering problem. At Harvard he also fell under the influence of J. H. Van Vleck and developed an interest in solid state physics.
Kohn made significant contributions to semiconductor physics, which led to his award of the Oliver E. Buckley Prize by the American Physical Society. He was also awarded the Feenburg medal for his contributions to the many-body problem.
His work on density functional theory was initiated during a visit to the École Normale Supérieure in Paris, with Pierre Hohenberg, and was prompted by a consideration of alloy theory. The
Hohenberg–Kohn theorem was further developed, in collaboration with Lu Jeu Sham, to produce the Kohn-Sham equations. The latter is the standard work horse of modern materials science,[12] and even used in quantum theories of plasmas.[12]
In 2004, a study of all citations to the Physical Review journals from 1893 until 2003, found Kohn to be an author of five of the 100 papers with the "highest citation impact", including the first two.[13]
W. Kohn, "An essay on condensed matter physics in the twentieth century," Reviews of Modern Physics, Vol. 71, No. 2, pp. S59–S77, Centenary 1999. APS
W. Kohn, "Nobel Lecture: Electronic structure of matter — wave functions and density functionals," Reviews of Modern Physics, Vol. 71, No. 5, pp. 1253–1266 (1999). APS
D. Jérome, T.M. Rice, and W. Kohn, "Excitonic Insulator," Physical Review, Vol. 158, No. 2, pp. 462–475 (1967). APS
P. Hohenberg, and W. Kohn, "Inhomogeneous Electron Gas," Physical Review, Vol. 136, No. 3B, pp. B864–B871 (1964). APS
W. Kohn, and L. J. Sham, "Self-Consistent Equations Including Exchange and Correlation Effects," Physical Review, Vol. 140, No. 4A, pp. A1133–A1138 (1965). APS
W. Kohn, and J. M. Luttinger, "New Mechanism for Superconductivity," Physical Review Letters, Vol. 15, No. 12, pp. 524–526 (1965). APS
W. Kohn, "Theory of the Insulating State," Physical Review, Vol. 133, No. 1A, pp. A171–A181 (1964). APS
W. Kohn, "Cyclotron Resonance and de Haas-van Alphen Oscillations of an Interacting Electron Gas," Physical Review, Vol. 123, pp. 1242–1244 (1961). APS
^Tegmark, Max (February 19, 2013). "Top Scientists On God: Who Believes, Who Doesn't". The Huffington Post. Archived from the original on February 26, 2013. Retrieved May 13, 2013. I am very much a scientist, and so I naturally have thought about religion also through the eyes of a scientist. When I do that, I see religion not denominationally, but in a more, let us say, deistic sense. I have been influenced in my thinking by the writing of Einstein who has made remarks to the effect that when he contemplated the world he sensed an underlying Force much greater than any human force. I feel very much the same. There is a sense of awe, a sense of reverence, and a sense of great mystery.
^ abE. K. U. Gross and R. M. Dreizler, Density Functional Theory, Plenum 1993
^Redner, S. Citation Statistics From More Than a Century of Physical Review 2004 Redner, S (2004). "Citation Statistics from More Than a Century of Physical Review". arXiv:physics/0407137.
^"Walter Kohn". American Academy of Arts & Sciences. Retrieved January 26, 2022.
^"Walter Kohn". www.nasonline.org. Retrieved January 26, 2022.
Walter Kohn on Nobelprize.org including the Nobel Lecture, January 28, 1999 (a year later) Electronic Structure of Matter – Wave Functions and Density Functionals
Kohn's faculty website at University of California-Santa Barbara. Retrieved November 11, 2006.