His original research in developing the technique of flash photolysis to obtain information on short-lived molecular species provided the first evidence of free radicals. His later research utilised the technique to study the detailed aspects of the light-dependent reactions of photosynthesis, with particular regard to possible applications to a hydrogen economy, of which he was a strong advocate.
Porter served as professor in the Chemistry department at the University of Sheffield in 1954–65. It was here he started his work on flash photolysis with equipment designed and made in the departmental workshop. During this tenure he also took part in a television programme describing his work. This was in the "Eye on Research" series. Porter became Fullerian Professor of Chemistry and Director of the Royal Institution in 1966. During his directorship of the Royal Institution, Porter was instrumental in the setting up of Applied Photophysics, a company created to supply instrumentation based on his group's work. He was awarded the Nobel Prize in Chemistry in 1967 along with Manfred Eigen and Ronald George Wreyford Norrish.[10] In the same year he became a visiting professor at University College London.[10]
He was knighted in 1972, appointed to the Order of Merit in 1989,[14] and was made a life peer as Baron Porter of Luddenham, of Luddenham in the County of Kent, in 1990. In 1995, he was awarded an Honorary Degree (Doctor of Laws) from the University of Bath.[15]