*Club domestic league appearances and goals, correct as of 15 May 2022 ‡ National team caps and goals, correct as of 20 July 2023 (prior the 2023 FIFA Women's World Cup)
Matlou came to prominence within the national team by scoring six goals at the 2008 African Women's Championship.[5] She has been selected for the squads for a variety of tournaments, including at the 2012 Summer Olympics in London, United Kingdom.[2] In 2014, South Africa's coachVera Pauw deployed Matlou—previously a striker, as a defender.[7]