Defending champion Serena Williams defeated Sara Errani in the final, 6–3, 6–0 to win the women's singles tennis title at the 2014 Italian Open.
Maria Sharapova's loss in the third round ended her 16-match winning streak in the tournament dating back to 2008. The streak includes two Italian Open titles. She would go on to win her third and last title in Rome in following year.
Seeds
The top eight seeds receive a bye into the second round.