螺［3.3］庚烷-2-甲酸

螺［3.3］庚烷-2-甲酸
识别
CAS号 28114-87-6  checkY
SMILES
 
  • O=C(O)C1CC2(CCC2)C1
性质
化学式 C8H12O2
摩尔质量 140.18 g·mol−1
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

螺[3.3]庚烷-2-甲酸是一种有机化合物，化学式为C8H12O2。它可以以1,1-环丁烷二甲酸二乙酯为原料经多步反应制得。[1]它和氯化亚砜回流反应，可以得到螺[3.3]庚烷-2-甲酰氯。[2]它和红色氧化汞在四氯化碳中和溴反应，可以得到2-溴螺[3.3]庚烷。[3]

参考文献

  1. ^ Mingyang Ma; Younghwan Kwon. Simultaneous Enhancement of the Mechanical Properties, Performance and Insensitivity of an Energetic Elastomeric Polyurethane Binder by Kinetically Grafting Reactive Spiranes. Polymers 2023, 15 (23), 4564. doi:10.3390/polym15234564.
  2. ^ Cottrell, Kevin M.; Maxwell, John P. Piperidin-1-yl-N-pyridin-3-yl-2-oxoacetamide derivatives useful for the treatment of MTAP-deficient and/or MT-A accumulating cancers and their preparation. 2022. WO2022026892.
  3. ^ Charles Roberts, John C. Walton and Bernard Maillard. Spiro[3.3]alkyl and spiro[3.3]alkylmethyl radicals. J. Chem. Soc., Perkin Trans. 2, 1986, 305-311. doi:10.1039/P29860000305.

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