四甲基硒氰酸铵是一种化合物,化学式为(CH3)4NSeCN,它可由硒氰酸甲酯和三甲胺反应得到。[1]硒氰酸钾和四甲基溴化铵在乙腈中反应,浓缩溶液后,也能析出四甲基硒氰酸铵晶体。[2]它的水溶液被溴的苯溶液氧化,可以得到[(CH3)4N](SeCN)3。[3]它和磺酰氯的乙腈溶液反应,得到四甲基二氯硒氰酸铵((CH3)4NSeCl2CN)。[2]
参考文献
- ^ 1.0 1.1 C. R. McCrosky, F. W. Bergstrom, G. Waitkins. Reactions of Nitriles and Related Compounds with Sulfur in the Presence of Amines; Synthesis of Quaternary Ammonium Thiocyanates 1. Journal of the American Chemical Society. 1940-08, 62 (8): 2031–2034 [2020-04-30]. ISSN 0002-7863. doi:10.1021/ja01865a033 (英语).
- ^ 2.0 2.1 Kenneth J. Wynne, J. Golen. Chalcogen chemistry. IX. Synthesis of alkylamonium dihalocyanoseleate(II) and trihaloselenate(II) salts. Inorganic Chemistry. 1974-01, 13 (1): 185–189 [2020-04-30]. ISSN 0020-1669. doi:10.1021/ic50131a036 (英语).
- ^ Sverre Hauge, Ella C. Kimmel, Beryl Holm, Gunnar Widmark, J. Koskikallio, Sukeji Kachi. Syntheses and Crystal Data on Salts of the Triselenocyanate and Seleniumtriselenocyanate Ions.. Acta Chemica Scandinavica. 1971, 25: 3081–3093 [2020-04-30]. ISSN 0904-213X. doi:10.3891/acta.chem.scand.25-3081. (原始内容存档于2018-06-02) (英语).
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HSeCN
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He
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Li
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Be
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B
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C
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N
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O
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F
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Ne
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NaSeCN
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Mg
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Al
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Si
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P
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S
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Cl
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Ar
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KSeCN
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Ca
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Sc
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Ti
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V
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Cr
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Mn
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Fe
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HgCo(NCSe)4
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Ni
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CuSeCN
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Zn(SeCN)2
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Ga
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Ge
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As
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Se
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Br
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Kr
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Rb
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Sr
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Y
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Zr
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Nb
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Mo
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Tc
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Ru
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Rh
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Pd
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AgSeCN
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Cd
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In
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Sn
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Sb
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Te
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I
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Xe
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Cs
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Ba
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镧系
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Hf
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Ta
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W
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Re
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Os
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Ir
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Pt
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Au
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Hg(SeCN)2
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Tl
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Pb(SeCN)2
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Bi
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Po
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At
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Rn
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Fr
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Ra
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锕系
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Rf
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Db
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Sg
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Bh
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Hs
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Mt
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Ds
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Rg
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Cn
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Nh
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Fl
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Mc
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Lv
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Ts
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Og
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↓
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镧系
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La
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Ce
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Pr
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Nd
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Pm
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Sm
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Eu
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Gd
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Tb
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Dy
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Ho
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Er
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Tm
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Yb
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Lu
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锕系
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Ac
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Th
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Pa
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U
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Np
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Pu
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Am
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Cm
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Bk
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Cf
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Es
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Fm
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Md
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No
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Lr
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