超临界CO2(SFE) 是一种绿色的提取方法,使用超临界 CO2 作为溶剂。超临界 CO2 的临界点为 31.1 °C 和 73.8 bar,此时 CO2 的密度与液体相近,但是具有气体的扩散性。超临界 CO2 的极性较低,因此对于极性化合物的溶解度较低,但是对于非极性化合物的溶解度较高。此外,超临界 CO2 的粘度低,有利于扩散。超临界 CO2 的温度较低,因此对于热敏感的聚合物有利。
^"Characteristic and Synthetic Approach of Molecularly Imprinted Polymer" Int. J. Mol. Sci. 2006, 7, 155–178
^Mosbach H. Molecularly Imprinted Polymers and Their Use in Biomimetic Sensors. Chem Rev. 2000.
^Sellergren B, Buechel G. A porous, molecularly imprinted polymer and preparation. PCT Int. Appl. 1999.
^Nematollahzadeh A, Sun W, Aureliano CS, Lütkemeyer D, Stute J, Abdekhodaie MJ, et al. High-capacity hierarchically imprinted polymer beads for protein recognition and capture. Angewandte Chemie. January 2011, 50 (2): 495–8. PMID 21140388. doi:10.1002/anie.201004774.
^Xu J, Prost E, Haupt K, Bui TS. Direct and Sensitive Determination of Trypsin in Human Urine Using a Water-Soluble Signaling Fluorescent Molecularly Imprinted Polymer Nanoprobe. Sensors and Actuators. 2017, 258: 10–17. doi:10.1016/j.snb.2017.11.077.
^Cowen T, Karim K, Piletsky S. Computational approaches in the design of synthetic receptors - A review. Analytica Chimica Acta. September 2016, 936: 62–74. PMID 27566340. doi:10.1016/j.aca.2016.07.027.
^Piletsky SA, Karim K, Piletska EV, Day CJ, Freebairn KW, Legge C, Turner AP. Recognition of ephedrine enantiomers by molecularly imprinted polymers designed using a computational approach. Analyst. 2001, 126 (10): 1826–1830. Bibcode:2001Ana...126.1826P. S2CID 97971902. doi:10.1039/b102426b.
^Khan MS, Pal S, Krupadam RJ. Computational strategies for understanding the nature of interaction in dioxin imprinted nanoporous trappers. Journal of Molecular Recognition. July 2015, 28 (7): 427–37. PMID 25703338. S2CID 23551720. doi:10.1002/jmr.2459.
^Golker K, Nicholls IA. The effect of crosslinking density on molecularly imprinted polymer morphology and recognition. European Polymer Journal. 2016, 75: 423–430. doi:10.1016/j.eurpolymj.2016.01.008.
^Cowen T, Busato M, Karim K, Piletsky SA. In Silico Synthesis of Synthetic Receptors: A Polymerization Algorithm. Macromolecular Rapid Communications. December 2016, 37 (24): 2011–2016. PMID 27862601. doi:10.1002/marc.201600515. hdl:2381/40379.
^Piletska EV, Guerreiro A, Mersiyanova M, Cowen T, Canfarotta F, Piletsky S, et al. Probing Peptide Sequences on Their Ability to Generate Affinity Sites in Molecularly Imprinted Polymers. Langmuir. January 2020, 36 (1): 279–283. PMID 31829602. S2CID 36207119. doi:10.1021/acs.langmuir.9b03410.
^Levi L, Raim V, Srebnik S. A brief review of coarse-grained and other computational studies of molecularly imprinted polymers. Journal of Molecular Recognition. 2011, 24 (6): 883–91. PMID 22038796. S2CID 30296633. doi:10.1002/jmr.1135.
^Srebnik S. Theoretical investigation of the imprinting efficiency of molecularly imprinted polymers. Chemistry of Materials. 2004, 16 (5): 883–888. doi:10.1021/cm034705m.
^Wulff G, Sarhan A, Zabrocki K. Enzyme-analogue built polymers and their use for the resolution of racemates.. Tetrahedron Letters. 1973, 14 (44): 4329–32. doi:10.1016/S0040-4039(01)87213-0.
^Olsen J, Martin P, Wilson ID. Molecular imprints as sorbents for solid phase extraction: potential and applications. Anal. Commun. 1998, 35 (10): 13H–14H. doi:10.1039/A806379F.
^Allender CJ, Richardson C, Woodhouse B, Heard CM, Brain KR. Pharmaceutical applications for molecularly imprinted polymers. International Journal of Pharmaceutics. February 2000, 195 (1–2): 39–43. PMID 10675681. doi:10.1016/s0378-5173(99)00355-5.
^Ramström O, Skudar K, Haines J, Patel P, Brüggemann O. Food analyses using molecularly imprinted polymers. Journal of Agricultural and Food Chemistry. May 2001, 49 (5): 2105–14. PMID 11368563. doi:10.1021/jf001444h.
^Wulff G, Gross T, Schönfeld R. Enzyme Models Based on Molecularly Imprinted Polymers with Strong Esterase Activity. Angewandte Chemie International Edition in English. 1997, 36 (18): 1962. doi:10.1002/anie.199719621.
^Olsen J, Martin P, Wilson ID. Molecular imprints as sorbents for solid phase extraction: potential and applications. Anal. Commun. 1998, 35 (10): 13H–14H. doi:10.1039/A806379F.
^Allender CJ, Richardson C, Woodhouse B, Heard CM, Brain KR. Pharmaceutical applications for molecularly imprinted polymers. International Journal of Pharmaceutics. February 2000, 195 (1–2): 39–43. PMID 10675681. doi:10.1016/s0378-5173(99)00355-5.
^Ellwanger A, Berggren C, Bayoudh S, Crecenzi C, Karlsson L, Owens PK, et al. Evaluation of methods aimed at complete removal of template from molecularly imprinted polymers. The Analyst. June 2001, 126 (6): 784–92. Bibcode:2001Ana...126..784E. PMID 11445938. doi:10.1039/b009693h.
^Soxhlet, F. "Die gewichtsanalytische Bestimmung des Milchfettes". Polytechnisches J. (Dingler's) 1879, 232, 461.
^Cintas P, Luche JL. Green chemistry. The sonochemical approach. Green Chem. 1999, 1 (3): 115–125. doi:10.1039/a900593e.
^Luque-Garcia JL, de Castro L. Ultrasound: A powerful tool for leaching. Trends Anal. Chem. 2003, 22: 90–99. doi:10.1016/S0165-9936(03)00102-X.
^Ellwanger A, Berggren C, Bayoudh S, Crecenzi C, Karlsson L, Owens PK, et al. Evaluation of methods aimed at complete removal of template from molecularly imprinted polymers. The Analyst. June 2001, 126 (6): 784–92. Bibcode:2001Ana...126..784E. PMID 11445938. doi:10.1039/b009693h.
^Tobiszewski M, Mechlińska A, Zygmunt B, Namieśnik J. Green analytical chemistry in sample preparation for determination of trace organic pollutants. Trends Anal. Chem. 2009, 28 (8): 943–951. doi:10.1016/j.trac.2009.06.001.