二氰合金(I)酸铊(I)

二氰合金(I)酸铊(I)
识别
CAS号 15634-30-7  checkY
SMILES
 
  • [Tl+].N#[C-][Au+][C-]#N
性质
化学式 Tl[Au(CN)2]
摩尔质量 453.38 g·mol⁻¹
外观 浅黄色固体[1]
密度 6.105 g/cm3（298 K）[2]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

二氰合金(I)酸铊(I)是一种配位化合物，化学式为Tl[Au(CN)2]。它可由氰化亚铊和氰化亚金在煮沸的水溶液中反应得到[1]，或由硫酸亚铊（或硝酸亚铊[3]）和氰亚金酸钾的复分解反应制得[2]。其分子存在Tl-Au相互作用。[3]

参考文献

  1. ^ 1.0 1.1 H. Stammreich; B.M. Chadwick; S.G. Frankiss (1968). Vibrational spectrum and structure of solid TlAu(CN)2. Journal of Molecular Structure, 1(3), 191–196. doi:10.1016/0022-2860(68)87002-4.
  2. ^ 2.0 2.1 Thallium dicyanoaurate(I), Tl[Au(CN)2], and cesium dicyanoaurate(I), Cs[Au(CN)2]. Acta Cryst, 1984. C40: 1767–1769. doi:10.1107/s0108270184009471
  3. ^ 3.0 3.1 Photoluminescence and electronic structure of thallium(1+) dicyanoaurate(1-): evidence for relativistic effects in thallium-gold and gold-gold interactions. Inorg. Chem. 1991, 30, 14, 2868–2876. doi:10.1021/ic00014a010.

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