二(三氟甲基)硒是一种有机硒化合物，化学式为(CF3)2Se。它可由三氟碘甲烷和硒反应制得，该反应还会产生少量的二(三氟甲基)二硒。[2]它可以被一氟化氯[3]或二氟化氙[4]氧化为二(三氟甲基)二氟化硒。它与硫类似物不同，对水或碱的水溶液稳定，但是在100 °C下，它可以被氢氧化钾的醇溶液分解。[2]
参考文献
- ^ Bowen, H. J. M. The structures of some trifluoromethyl derivatives of group 6. Transactions of the Faraday Society (Royal Society of Chemistry (RSC)). 1954, 50: 452. ISSN 0014-7672. doi:10.1039/tf9545000452.
- ^ 2.0 2.1 2.2 Dale, J. W.; Emeléus, H. J.; Haszeldine, R. N. 599. Organometallic and organometalloidal fluorine compounds. Part XIV. Trifluoromethyl derivatives of selenium. J. Chem. Soc. (Royal Society of Chemistry (RSC)). 1958, 0 (0): 2939–2945. ISSN 0368-1769. doi:10.1039/jr9580002939.
- ^ Lau, Clement; Passmore, Jack. Some new perfluoroalkyl derivatives of SeF4 and SeF6. Journal of Fluorine Chemistry (Elsevier BV). 1976, 7 (1-3): 261–300. ISSN 0022-1139. doi:10.1016/s0022-1139(00)84002-6.
- ^ Baxter, Paul L.; Downs, Anthony J.; Forster, Alan M.; Goode, Michael J.; Rankin, David W. H.; Robertson, Heather E. The molecular structure of gaseous bis(trifluoromethyl)selenium difluoride as determined by electron diffraction. Journal of the Chemical Society, Dalton Transactions (Royal Society of Chemistry (RSC)). 1985, (5): 941. ISSN 0300-9246. doi:10.1039/dt9850000941.
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