乙酰丙酮双氧钼是钼的乙酰丙酮配合物之一,化学式为MoO2(acac)2。
制备
乙酰丙酮钼可由三氧化钼和乙酰丙酮在氨水中反应,硝酸酸化得到。[2]二乙氧基二氧化钼和乙酰丙酮在甲苯中反应,也能得到乙酰丙酮双氧钼。[3]
参考文献
- ^ 1.0 1.1 Molybdenum(VI) oxide bis(2,4-pentanedionate) 化学品安全技术说明书. Alfa Aesar. [2017-12-1]
- ^ Francisco J. Arnaiz. Microscale synthesis of MoO2(acac)2. Journal of Chemical Education, 1995. 72 (1): A7-A8. DOI:10.1021/ed072pA7.
- ^ Kim, Gyu Shik; Huffman, David; DeKock, Carroll W. Preparation and properties of dioxomolybdenum alkoxides, phenoxide, and siloxides prepared by the cocondensation reaction of molybdenum trioxide with alkoxy- or (aryloxy)silanes. Inorganic Chemistry, 1989. 28(7): 1279-1283. DOI:10.1021/ic00306a015.
拓展阅读
- Bartecki, Adam; Dembicka, Danuta. Structure and properties of oxycations. III. Molybdenyl compounds. Roczniki Chemii, 1965. 39(12): 1783-1798.
- Afanas'ev, O. P.; Bantysh, A. N.; Knyazev, D. A. Acetylacetonates of molybdenum(VI) and molybdenum(V). Zhurnal Neorganicheskoi Khimii, 1968. 13(2): 352-358.