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三乙烯基环三硼氧烷
| 三乙烯基环三硼氧烷
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IUPAC名
2,4,6-tris(ethenyl)-1,3,5,2,4,6-trioxatriborinane
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| 别名
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Trivinylboroxin, triethenylboroxin, 2,4,6-trivinyl-1,3,5,2,4,6-trioxatriborinane, 2,4,6-trivinylcyclotriboroxane
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| 识别
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| CAS号
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92988-08-4
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| PubChem
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2734807
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| ChemSpider
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2016551
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| SMILES
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| InChI
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- 1S/C6H9B3O3/c1-4-7-10-8(5-2)12-9(6-3)11-7/h4-6H,1-3H2
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| InChIKey
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WBRSYBLNSTYNPP-UHFFFAOYSA-N
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| 性质
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| 化学式
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C6H9B3O3
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| 摩尔质量
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161.57 g·mol−1
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| 外观
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无色液体
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| 密度
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0.89 g/ml
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| 沸点
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114 °C（387 K）
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| 危险性
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GHS危险性符号
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| GHS提示词
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警告
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| H-术语
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H302, H315, H319, H335
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| P-术语
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P261, P264, P264+265, P270, P271, P280, P301+317, P302+352, P304+340, P305+351+338, P319, P321, P330, P332+317
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| 主要危害
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可溶
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| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。
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三乙烯基环三硼氧烷是一种有机硼化合物，是环三硼氧烷的一种。
它可由硼酸三甲酯和乙烯基溴化镁反应制得。[1]
应用
三乙烯基环三硼氧烷可用于制备苯乙烯衍生物[2]及乙烯酯。[3]
参考文献
- ^ Bower, John F.; Williams, Andrew J.; Woodward, Hannah L.; Szeto, Peter; Lawrence, Ron M.; Gallagher, Timothy. Reactivity of cyclic sulfamidates towards phosphonate-stabilised enolates: synthesis and applications of α-phosphono lactams. Organic & Biomolecular Chemistry. 2007, 5 (16): 2636–2644. PMID 18019539. doi:10.1039/B706315F.
- ^ Coleman, Claire M.; O'Shea, Donal F. New Organolithium Addition Methodology to Diversely Functionalized Indoles. Journal of the American Chemical Society. 1 April 2003, 125 (14): 4054–4055. PMID 12670219. doi:10.1021/ja034283h.
- ^ Staderini, Matteo; Gambardella, Alessia; Lilienkampf, Annamaria; Bradley, Mark. A Tetrazine-Labile Vinyl Ether Benzyloxycarbonyl Protecting Group (VeZ): An Orthogonal Tool for Solid-Phase Peptide Chemistry (PDF). Organic Letters. 1 June 2018, 20 (11): 3170–3173. PMID 29791161. doi:10.1021/acs.orglett.8b00898.
外部链接
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