1-金刚烷硫醇

1-金刚烷硫醇
识别
CAS号 34301-54-7  checkY
SMILES
 
  • SC12CC3CC(CC(C3)C1)C2
性质
化学式 C10H16S
摩尔质量 168.3 g·mol−1
外观 白色固体[1]
熔点 100-102 °C[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

1-金刚烷硫醇是一种有机硫化合物，化学式为C10H15SH。它可由1-溴金刚烷、硫脲、氢溴酸和冰乙酸回流反应，再经氢氧化钠水解、盐酸酸化得到；[1]或由1-金刚烷醇和劳森试剂反应制得。[2]它可以被高锰酸钾氧化为二(1-金刚烷基)二硫。[3]

参考文献

  1. ^ 1.0 1.1 1.2 Studies on the diastereoselective oxidation of 1-thio-β-D-glucopyranosides: synthesis of the usually less favoured RS sulfoxide as a single diastereoisomer. Organic & Biomolecular Chemistry, 2015. doi:10.1039/C4OB02030H
  2. ^ S-alkyl Dithiocarbamates Synthesis through Electrochemical Multicomponent Reaction of Thiols, Hydrogen Sulfide, and Isocyanides. J. Org. Chem. 2023, 88, 17, 12311–12318. doi:10.1021/acs.joc.3c01017
  3. ^ Ground solid permanganate oxidative coupling of thiols into symmetrical/unsymmetrical disulfides: selective and improved process. Journal of Sulfur Chemistry, 2022. 43 (6). doi:10.1080/17415993.2022.2083914

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