间三联苯-4,4''-二甲酸

间三联苯-4,4''-二甲酸
别名 [1,1':3',1''-三联苯]-4,4''-二甲酸
1,3-二(羧基苯基)苯
识别
CAS号 13215-72-0  checkY
SMILES
 
  • O=C(O)C=1C=CC(=CC1)C=2C=CC=C(C2)C=3C=CC(=CC3)C(=O)O
性质
化学式 C20H14O4
摩尔质量 318.32 g·mol−1
外观 白色固体[1]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

间三联苯-4,4''-二甲酸是一种有机化合物，化学式为C20H14O4。它可由1,3-二溴苯和4-甲氧羰基苯硼酸在四(三苯基膦)钯催化下反应，再在氢氧化锂溶液中水解，经酸化制得。[1]它和硝酸铜[1]、四氯化锆[2]等金属盐反应，可以得到相应的金属有机框架材料。

参考文献

  1. ^ 1.0 1.1 1.2 A readily available urea based MOF that act as a highly active heterogeneous catalyst for Friedel-Crafts reaction of indoles and nitrostryenes. Catalysis Communications, 2018. doi:10.1016/j.catcom.2017.10.010.
  2. ^ Structural Regulation and Light Hydrocarbon Adsorption/Separation of Three Zirconium–Organic Frameworks Based on Different V-Shaped Ligands. ACS Appl. Mater. Interfaces 2021, 13, 35, 41680–41687. doi:10.1021/acsami.1c11224.

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