鎝(V)酸鈉 是一种无机化合物 ,化学式 为NaTcO3 ,是一种钙钛矿 材料。[ 1] 它可由锝 、高锝酸钠 和氧化钠 共热制得,高温下发生歧化。[ 2] 此外,Na2 99 MoO4 在NaOH溶液的衰变 也会产生NaTcO3 。[ 3] NaTcO3 的puckering效应比NaMoO3 小,eg π 和a1g 态间带消失。[ 4]
參考資料
^ Sabine Körbel, Miguel A. L. Marques, Silvana Botti. Stability and electronic properties of new inorganic perovskites from high-throughput ab initio calculations . Journal of Materials Chemistry C. 2016, 4 (15): 3157–3167 [2019-02-24 ] . ISSN 2050-7526 . doi:10.1039/C5TC04172D . (原始内容 存档于2019-07-01) (英语) .
^ 无机化学丛书. 第九卷 锰分族 铁系 铂系. pp 122. 3.11 氧化数为V的锝和铼化合物
^ M. Fis̆er, V. Brabec, O. Dragoun, A. Kovalík, J. Frána, M. Rys̆avý. Determination of 99mTc valent form in solids by measurement of internal conversion electrons . The International Journal of Applied Radiation and Isotopes. 1985-3, 36 (3): 219–222 [2019-02-24 ] . doi:10.1016/0020-708X(85)90071-7 . (原始内容 存档于2018-07-02) (英语) .
^ M. H. N. Assadi, Masashi Okubo, Atsuo Yamada, Yoshitaka Tateyama. Oxygen redox in hexagonal layered Na x TMO 3 (TM = 4d elements) for high capacity Na ion batteries . Journal of Materials Chemistry A. 2018, 6 (8): 3747–3753 [2019-02-24 ] . ISSN 2050-7488 . doi:10.1039/C7TA10826E . (原始内容 存档于2019-07-01) (英语) .
拓展阅读
Keller, C.; Kanellakopulos, B. Ternary oxides of tri- to septivalent technetium and alkali metals. Journal of Inorganic and Nuclear Chemistry (1965), 27(4), 787-795.
Kanellakopulos, Basil. The ternary oxide of 3-to 7-valent technetium with alkalis. (1964), (AEC Accession No. 31424, Rept. No. KFK-197), 73 pp.
锝(I) 锝(III) 锝(IV) 锝(V) 锝(VI) 锝(VII) 非整数价态