鎝(V)酸鈉

鎝(V)酸鈉
英文名	Sodium technetate(V)
识别
CAS号	12034-16-1
SMILES	[Na+].[O-][Tc](=O)=O;
性质
化学式	NaTcO3
摩尔质量	168.99 g·mol⁻¹
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

鎝(V)酸鈉是一种无机化合物，化学式为NaTcO₃，是一种钙钛矿材料。^[1]它可由锝、高锝酸钠和氧化钠共热制得，高温下发生歧化。^[2]此外，Na₂⁹⁹MoO₄在NaOH溶液的衰变也会产生NaTcO₃。^[3]NaTcO₃的puckering效应比NaMoO₃小，e_g^π和a_1g态间带消失。^[4]

參考資料

^ Sabine Körbel, Miguel A. L. Marques, Silvana Botti. Stability and electronic properties of new inorganic perovskites from high-throughput ab initio calculations. Journal of Materials Chemistry C. 2016, 4 (15): 3157–3167 [2019-02-24]. ISSN 2050-7526. doi:10.1039/C5TC04172D. （原始内容存档于2019-07-01）（英语）.
^ 无机化学丛书. 第九卷锰分族铁系铂系. pp 122. 3.11 氧化数为V的锝和铼化合物
^ M. Fis̆er, V. Brabec, O. Dragoun, A. Kovalík, J. Frána, M. Rys̆avý. Determination of 99mTc valent form in solids by measurement of internal conversion electrons. The International Journal of Applied Radiation and Isotopes. 1985-3, 36 (3): 219–222 [2019-02-24]. doi:10.1016/0020-708X(85)90071-7. （原始内容存档于2018-07-02）（英语）. 请检查|date=中的日期值 (帮助)
^ M. H. N. Assadi, Masashi Okubo, Atsuo Yamada, Yoshitaka Tateyama. Oxygen redox in hexagonal layered Na x TMO 3 (TM = 4d elements) for high capacity Na ion batteries. Journal of Materials Chemistry A. 2018, 6 (8): 3747–3753 [2019-02-24]. ISSN 2050-7488. doi:10.1039/C7TA10826E. （原始内容存档于2019-07-01）（英语）.

拓展阅读

Keller, C.; Kanellakopulos, B. Ternary oxides of tri- to septivalent technetium and alkali metals. Journal of Inorganic and Nuclear Chemistry (1965), 27(4), 787-795.
Kanellakopulos, Basil. The ternary oxide of 3-to 7-valent technetium with alkalis. (1964), (AEC Accession No. 31424, Rept. No. KFK-197), 73 pp.