烯丙基缩水甘油醚

烯丙基缩水甘油醚
IUPAC名 2-(prop-2-enoxymethyl)oxirane
别名	2-[(Allyloxy)methyl]oxirane 1-Allyloxy-2,3-epoxypropane Glycidyl allyl ether [(2-Propenyloxy)methyl] oxirane[1]
识别
CAS号	106-92-3 ^Y
PubChem	7838
ChemSpider	13836520
SMILES	C=CCOCC1CO1
InChI	1/C6H10O2/c1-2-3-7-4-6-5-8-6/h2,6H,1,3-5H2
InChIKey	LSWYGACWGAICNM-UHFFFAOYAR
EINECS	203-442-4
性质
化学式	C6H10O2
摩尔质量	114.14 g·mol^−1
外观	无色液体[1]
氣味	pleasant[1]
密度	0.97 g/mL (20 °C)[1]
熔点	-100 °C（173 K）
沸点	154 °C（427 K）
溶解性（水）	14% (20°C)[1]
溶解性（有机溶剂）	混溶（丙酮、甲苯、辛烷）[2]
蒸氣壓	2 mmHg (20 °C)[1]
折光度n D	1.4348 (20 °C)[2][3]
危险性
GHS提示词	危险
H-术语	H226, H351, H341, H332, H302, H335, H315, H318, H317, H412
主要危害	poisonous, mild irritant[2]
PEL	10 ppm (45 mg/m^3)[1]
致死量或浓度：
LC50（中位浓度）	270 ppm (mouse, 4 hr) 670 ppm (rat, 8 hr)[4]
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

烯丙基缩水甘油醚是一种有机化合物，化学式为C₆H₁₀O₂。

合成

烯丙基缩水甘油醚在商业上通过环氧氯丙烷和烯丙醇在碱存在下醚化制得：^[5]

The synthesis of allyl glycidyl ether by condensation of allyl alcohol and epichlorohydrin

它也可由烯丙醚（日语：アリルエーテル）的单环氧化反应得到：^[6]

The synthesis of allyl glycidyl ether by epoxidation of diallyl ether

参考文献

1. NIOSH Pocket Guide to Chemical Hazards. #0019. NIOSH. 
2. CID 7838 from PubChem
3. Clayton, G. D. and F. E. Clayton (eds.). Patty's Industrial Hygiene and Toxicology: Volume 2A, 2B, 2C: Toxicology. 3rd ed. New York: John Wiley Sons, 1981-1982., p. 2199
4. Allyl glycidyl ether. Immediately Dangerous to Life and Health Concentrations (IDLH). National Institute for Occupational Safety and Health (NIOSH). 
5. Clayton, G. D.; Clayton, F. E. (编). Patty's Industrial Hygiene and Toxicology. 2A, 2B, 2C: Toxicology 3rd. New York: John Wiley Sons. 1981–1982: 2197. 
6. Wróblewska, Agnieszka; Drewnowska, E.; Gawarecka, A. The epoxidation of diallyl ether to allyl-glycidyl ether over the TS-1 catalyst. Reaction Kinetics, Mechanisms and Catalysis. August 2016, 118 (2): 719–931. S2CID 101802831. doi:10.1007/s11144-016-1028-3.