氟硼酸锰是一种无机化合物,化学式为Mn(BF4)2。它的水合物和氟硼酸三乙基𨦡在无水乙腈中反应,可以得到[Mn(CH3CN)4](BF4)2(这一化合物也可由Mn和NOBF4反应得到)[2];和3(5)-甲基吡唑(MPZ)在原甲酸三乙酯存在下于乙醇中反应,可以得到Mn4F4(MPZ)12(BF4)4。[3]
六水合物[Mn(H2O)6](BF4)2在162 K和223 K发生相变。[4]
参考文献
- ^ K. C. Moss, D. R. Russell, D. W. A. Sharp. The lattice constants of some metal-fluoroborate hexahydrates. Acta Crystallographica. 1961-03-01, 14 (3): 330–330 [2022-06-22]. ISSN 0365-110X. doi:10.1107/S0365110X61001133. (原始内容存档于2022-06-22).
- ^ Dimitri Coucouvanis (编). Useful Reagents and Ligands: Useful Reagents and Ligands. New York, USA: John Wiley & Sons, Inc. 2002-04-07: 75–121 [2022-06-22]. ISBN 9780471208259. doi:10.1002/0471224502.ch2. (原始内容存档于2022-06-08).
- ^ Richard W.M. Ten Hoedt, Jan Reedijk. Synthesis, characterization and magnetic behaviour of tetra-μ3-fluorododecakis(5-methylpyrazole-N2)tetrametal(II) tetrakis(tetrafluoroborates). Inorganica Chimica Acta. 1981-01, 51: 23–27 [2022-06-22]. doi:10.1016/S0020-1693(00)88311-5. (原始内容存档于2018-06-07) (英语).
- ^ E. Mikuli, A. Migdał-Mikuli, I. Natkaniec, B. Grad. Phase Transitions and Water Dynamics of [Co(H 2 O) 6 ](ClO 4 ) 2 and [Mn(H 2 O) 6 ](BF 4 ) 2 Studied by Neutron Scattering Methods. Zeitschrift für Naturforschung A. 2001-04-01, 56 (3-4): 244–248 [2022-06-22]. ISSN 1865-7109. doi:10.1515/zna-2001-0302. (原始内容存档于2022-06-22) (英语).
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