四甲基臭氧化铵

四甲基臭氧化铵
识别
CAS号 78657-29-1  checkY
性质
化学式 C4H12NO3
摩尔质量 122.14 g·mol−1
外观 亮橙红色的透明晶体[1]
密度 1.269 g·cm−3
若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

四甲基臭氧化铵是一种臭氧化物，化学式为[(CH3)4N]O3。它可由四甲基氢氧化铵和稀释的臭氧反应得到，产物难溶于甲胺，反应生成的水可通过甲胺萃取来除去。[2]此外，四甲基超氧化铵和臭氧化钾在液氨中的反应也能得到四甲基臭氧化铵。[3]它是正交晶系晶体，具有CsCl结构。[3][1]它比碱金属臭氧化物更稳定，于75 °C分解。它在100 °C的分解产物有三甲胺、氧气、二甲醚、甲醇等物质。[4]

相关化合物

四乙基臭氧化铵（[(C2H5)4N]O3，CAS: 133324-06-8）是亮宝石红色晶体，分子中β-H的存在使之稳定性变低，30~40 °C即可分解生成三乙胺、乙烯和氧气。[1]

参考文献

  1. ^ 1.0 1.1 1.2 Werner Hesse, Martin Jansen. New ionic ozonides: syntheses, structures, and properties of N(CH3)4O3 and N(C2H5)4O3. Inorganic Chemistry. 1991-11, 30 (23): 4380–4385 [2021-11-16]. ISSN 0020-1669. doi:10.1021/ic00023a018 （英语）. 
  2. ^ Irvine J. Solomon, Andrew J. Kacmarek, John M. McDonough, Kiyo Hattori. Preparation, Characterization and Physical and Chemical Properties of Tetramethylammonium Ozonide 1. Journal of the American Chemical Society. 1960-11, 82 (21): 5640–5641 [2021-11-16]. ISSN 0002-7863. doi:10.1021/ja01506a022. （原始内容存档于2021-11-16） （英语）. 
  3. ^ 3.0 3.1 Werner Hesse, Martin Jansen. Ein neuer Zugang zu ionischen Ozoniden. Angewandte Chemie. 1988-10, 100 (10): 1388–1389 [2021-11-16]. doi:10.1002/ange.19881001015. （原始内容存档于2021-11-16） （德语）. 
  4. ^ Werner Hesse, Martin Jansen, Wolfgang Schnick. Recent results in solid state chemistry of ionic ozonides, hyperoxides, and peroxides. Prog. Solid St. Chem., 1989. 19: 47-110.

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