Klor tetroksit

Klor tetroksit, ClO4 kimyasal formüllü bir klor oksit.

Tarihi

Gomberg'in 1923'te yaptığı üretim

1923'te, ünlü radikal kimyageri Moses Gomberg bir klor tetroksit üretim metodu öne sürdü. Moses, iyot ile gümüş perkloratın, susuz dietil eter içindeki tepkimesinin klor tetroksiti vereceğini iddia etti.[1]

I2 + 2 AgClO4 → 2 AgI + (ClO4)2

Ancak daha sonraki araştırmalar, bahsi geçen tepkime ürününün iyot perklorat olduğunu iddia etti.[2] Şimdiye kadar iyot perklorat oluşumuna dair bir kanıt bulunmamaktadır.

Eachus'un 1968 üretimi

1968'de, Eachus potasyum kloratı 77 Kelvinde gama ışınlarına maruz bırakarak klor tetroksiti üretti.

Kaynakça

  1. ^ Gomberg, M. (1 Şubat 1923). "The Reaction Between Silver Perchlorate and Iodine. Chlorine Tetra-Oxide". Journal of the American Chemical Society. 45 (2). ss. 398-421. doi:10.1021/ja01655a017. 
  2. ^ Alcock, N. W.; Waddington, T. C. (1 Ocak 1962). "478. The reaction between iodine and silver perchlorate". Journal of the Chemical Society (Resumed). s. 2510. doi:10.1039/JR9620002510. 

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