Dimethyl peroxide

Dimethyl peroxide is an organic compound with the chemical formula H3COOCH3. It is the simplest organic peroxide, a type of organic compound with a C−O−O�

Dimethyl peroxide
Dimethyl peroxide
Dimethyl peroxide
Names
IUPAC name
Methylperoxymethane[1]
Other names
  • Dimethyl peroxide
  • Dimethyldioxidane
Identifiers
3D model (JSmol)
Beilstein Reference 1730817
ChEBI
ChemSpider
Gmelin Reference 305275
  • COOC
Properties
CH3OOCH3
Molar mass 62.07 g·mol−1
Appearance Colorless volatile liquid[2][1]
Odor Sharp[3]
Density About 0.85 g/cm3[2]
Boiling point About 35 °C[2]
Soluble[2]
Solubility Soluble in organic solvents but less so in water.[2]
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Explosive[2][4]
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references


Dimethyl peroxide is an organic compound with the chemical formula H3COOCH3. It is the simplest organic peroxide, a type of organic compound with a C−O−O−C pattern of chemical bonds. Like most organic peroxides, it is an unstable compound that is explosive at room temperature.

Chemistry

The bond between the oxygen atoms is very weak, and often breaks apart into methoxy radicals. These radicals make dimethyl peroxide a useful radical initiator for polymerisation, but also make it dangerously reactive.[source?]

References

  1. 1.0 1.1 "Dimethyl peroxide". pubchem.ncbi.nlm.nih.gov.
  2. 2.0 2.1 2.2 2.3 2.4 2.5 "Buy Dimethyl peroxide (EVT-1549083) | 690-02-8".[permanent dead link]
  3. Chemistry, Anxin (October 6, 2025). "dimethyl peroxide - Cangzhou Bohai New District Anxin Chemistry Co.,Ltd".
  4. "DIMETHYLHEXANE DIHYDROPEROXIDE, WITH 18% OR MORE WATER | CAMEO Chemicals | NOAA".


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