Zirconium phosphide
Names
IUPAC name
Phosphinidinzirconium
Identifiers
ChemSpider
EC Number
InChI=1S/P.Zr
Key: VQYKQHDWCVUGBB-UHFFFAOYSA-N
Properties
P Zr
Molar mass
−1
Appearance
solid
Hazards
GHS labelling
Except where otherwise noted, data are given for materials in their
standard state (at 25 °C [77 °F], 100 kPa).
Chemical compound
Zirconium monophosphide is a binary inorganic compound of zirconium metal and phosphorus with the chemical formula ZrP .[ 1] [ 2] [ 3]
Preparation
Zirconium monophosphide can be prepared from direct reaction of zirconium powders with red phosphorus :[ 4]
4 Zr + P4 → 4 ZrP
Physical properties
The α -form of zirconium monophosphide has a NaCl crystal structure.[ 5] β -form structure is hexagonal. The α -form is a superconductor if cooled below 5K.[ 6]
References
^ "Zirconium Phosphide" . American Elements . Retrieved 7 March 2024 .^ Irani, K. S.; Gingerich, K. A. (1 October 1963). "Structural transformation of zirconium phosphide" . Journal of Physics and Chemistry of Solids 24 (10): 1153–1158. doi :10.1016/0022-3697(63)90231-2 . ISSN 0022-3697 . Retrieved 7 March 2024 . ^ O'Bannon, Loran (6 December 2012). Dictionary of Ceramic Science and Engineering Springer Science & Business Media . p. 283. ISBN 978-1-4613-2655-7 . Retrieved 7 March 2024 . ^ Li, Zhen; Chen, Ning; Wang, Jigang; Li, Peishen; Guo, Ming; Wang, Qiang; Li, Chunhong; Wang, Changzheng; Guo, Tao; Chen, Shaowei (12 October 2017). "Efficient reduction of nitric oxide using zirconium phosphide powders synthesized by elemental combination method" (PDF) . Scientific Reports 7 (1): 13044. doi :10.1038/s41598-017-13616-5 . PMC 5638856 PMID 29026175 . ^ Swanson, Howard Eugene (1962). Standard X-ray Diffraction Powder Patterns: Data for 46 substances National Bureau of Standards . p. 75. Retrieved 7 March 2024 . ^ Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds CRC Press . p. 3769. ISBN 978-0-412-30120-9 . Retrieved 7 March 2024 .
Zr(II) Zr(III) Zr(IV) Acids and complexes Organozirconium(IV)
