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Octavio is a Spanish language masculine given name. In the Portuguese language the given name Octavio or Octávio is also found, but in Portuguese the normal spelling is Otávio. It is also used as a surname in the Philippines.

Individuals

Octavio Dotel, Major League Baseball relief pitcher
Octavio Paz Lozano, Mexican writer, poet, and diplomat, and the winner of the 1990 Nobel Prize for Literature
Octavio Ocampo, Mexican artist
Octavio Vazquez, Spanish-American composer
Octavio Zambrano, Ecuadorian soccer coach
Octavio Lugo, American entrepreneur, founder of StormTek, banker, businessman

A character in Scarface (1983 film)
A character in Eating Out 2: Sloppy Seconds
List of characters in King of the Hill § Other recurring characters, a character in King of the Hill
List of Sly Cooper characters § Octavio, a character from the video game Sly 3: Honor Among Thieves
The final boss of Splatoon
Octavio Silva, also known as Octane, a playable character in Apex Legends
Octavio the Octopus, an octopus who appeared in The Owl and the Octopus episode of Jim Henson's Animal Show

SD Octavio Vigo, a Spanish handball club based in Vigo, Galicia, Spain.
The name given by Jimi Hendrix to an effects pedal used with electric guitars, invented by Jim Morris of Kelsey-Morris Sound, London. A later version was called an Octavia (effects pedal)