Nueva Cáceres was considered the center of economy and industry in the Bicol Region, and the city was made capital of the province of Camarines. When the province was dissolved in 1829 and 1857, the city then became the capital of Camarines Sur. From 1902 until 1908, some villages of Canaman and Camaligan were annexed to the city.
On September 18, 1898, corporals Elias Angeles and Felix Plazo of the Guardia Civil planned a revolt to overthrow the Spanish colonial government and establish a republic. Their rebellion was successful, but it was short-lived. When the Americans arrived in Nueva Cáceres, they encountered no resistance and replaced the republican government with their own.
In 1919, under the Insular Government, most of Nueva Cáceres became part of the municipality of Naga, while several villages in the northwest were retroceded to their respective mother towns.
2Dissolved and divided between neighboring (sub-)provinces.
3Became the only sub-province left comprising Mountain Province in 1966, and therefore assumed the name of the mother province.
4Became the only sub-province left comprising Agusan in 1914, and therefore assumed the name of the mother province.
5Delimited to the downtown area of present-day Isabela City in 1973; dissolved in 1975.
6Legazpi City from 1948 to 1954 consisted of the present-day territories of Legazpi City and Daraga; this city was dissolved in 1954 into its two former constituent municipalities. Legazpi became a city on its own in 1959.