Nickel ternary chalcogenides

The Nickel ternary chalcogenides are a class of chemical compounds that contains nickel, a chalcogenide, and another element. Nickel forms a series of double nickel oxides with other elements, which may be termed "nickelates". These double nickel oxides are not listed on this page. There are also many well defined double compounds with sulfur, selenium and tellurium which are listed here.

formula	name	colour	structure	production	references
NH4NiS5	ammonium nickel sulphide	black		NH4 polysulfide+NiSO4	[1][2]
K2Ni3S4	potassium nickel tetrasulfide	bronze yellow	Fddd a=10.023 b=26.074 c=5.704	NiSO4 K2CO3 S	[1][3][4]
K2Ni11S10	potassium nickel decasulfide	dark metallic green		NiO+KCNS	[1] J. Milbauer
Na2Ni3S4	sodium nickel tetrasulfide	dark yellow		NiSO4 Na2CO3 S	[1] R. Schneider
KNi2S2	potassium dinickel disulfide	orange yellow		Ni foil, S, K at 723K	[5][6]
K2Ni3Se4	potassium nickel tetraselenide	gold	Fddd a=10.468 b=26.496 c=5.995		[7][8]
KNi2Se2	potassium dinickel diselenide	purple-red	I4/mmmtetragonal a=3.909, c=13.4142	Ni foil, Se shot, K at 723K	[5][9]
CsNi2Se2	caesium dinickel diselenide		tetragonal a=3.988, c=14.419	heat elements	[10]
TlNi2Se2	Thallium dinickel diselenide	gold metallic	tetragonal	heat elements together in closed quartz tube	[11]
Rb2Ni3S4	rubidium nickel tetrasulphide	metallic greenish gold	Fmmm orthorhombic a=9.901 Å, b=13.606 Å and c=5.861 Z=4 layered; ferromagnetic only after water immersion		[7][12]
Rb2Ni3Se4	rubidium nickel tetraselenide	golden metallic	Fddd orthorhombic a = 10.555 Å, b = 27.588 Å, c = 6.031 Å, Z = 8 layered; ferromagnetic only after water immersion	Rb2CO3 S Ni	[13]
Cs2Ni3S4	cesium nickel tetrasulphide	greenish gold	Fmmm a=10.038 b=14.552 c=5.934		[8][13]
Cs2Ni3S4	cesium nickel tetrasulphide	gold	Fmmm a=10.540 b=14.624 c=6.194		[8]
Cs0.9Ni3.1Se3			Hexagonal P63/m a = 9.26301(4) Å and c = 4.34272(2) Å	quasi-one-dimensional electric conductor	[14]
BaNi4S5	Barium nickel pentasulfide	bronze yellow		NiSO4 K2CO3 S	[1] R. Schneider; I. and L. Bellucci
Pb2Ni3S2	lead nickel disulfide	melt 790°		PbS Ni	[15] W Guertler; W Guertler H Schack
(Ni,Fe)9S8	Pentlandite	bronze yellow melt 870			[15] T. Scheerer
Fe2Ni2S4	ferrous nickel tetrasulfide	melt 840			[16] K Bornemann
Fe2Ni2S3	ferrous nickel trisulfide	stable over 575°, melt 886,			[17] K Bornemann
Fe3Ni4S5	ferrous nickel pentasulfide			below 575	[17] K Bornemann
Fe4Ni2S5					[17] K Bornemann
Fe2Ni3S4					[17] K Bornemann
Fe3Ni4S5					[17] K Bornemann
Fe2Ni2S3					[17] K Bornemann
FeNi2S4	Violarite	dark violet grey		mineral oxidate
Ni3Sn2S2					[18]
Ni3Bi2S2				superconducting	[18]
Ni3Bi2Se2				superconducting	[18]
NiSnS3	nickel thiostannate	greenish black	orthorhombic a=6.88 b=7.89 c=11.95 Z=8 V=644	NiCl2 + SnS2	[19]
NiGeS33	nickelselenogermanate				[20]
Ta2NiS5			Orthorhombic		[21]
Ta2NiSe5			monoclinic β=90.53		[21]
Ta2Ni2Te4					[22]
Ta2Ni3Te5					[22]

References

1. Mellor p443
2. Ephraim, Fritz (17 September 1923). "Über Nickelsulfid". Berichte der Deutschen Chemischen Gesellschaft (A and B Series) (in German). 56 (8): 1885–1886. doi:10.1002/cber.19230560825.
3. Bronger, W.; Eyck, J.; Rüdorff, W.; Stöussel, A. (July 1970). "Über Thio- und Selenoniccolate und -palladate der schweren Alkalimetalle". Zeitschrift für anorganische und allgemeine Chemie (in German). 375 (1): 1–7. doi:10.1002/zaac.19703750102.
4. Schneider, R. (1874). "Ueber neue Schwefelsalze". Annalen der Physik und Chemie. 227 (3): 437–450. Bibcode:1874AnP...227..437S. doi:10.1002/andp.18742270306.
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8. Bronger, W.; Rennau, R.; Schmitz, D. (May 1991). "Schichtstrukturen ternärer Chalkogenide ${\displaystyle {\ce {A2M3X4}}}$ (A ? K, Rb, Cs; M ? Ni, Pd, Pt; X ? S, Se)". Zeitschrift für anorganische und allgemeine Chemie. 597 (1): 27–32. doi:10.1002/zaac.19915970105.
9. Neilson, James R.; McQueen, Tyrel M. (9 May 2012). "Bonding, Ion Mobility, and Rate-Limiting Steps in Deintercalation Reactions with ${\displaystyle {\ce {ThCr2Si2}}}$ -type ${\displaystyle {\ce {KNi2 Se2}}}$". Journal of the American Chemical Society. 134 (18): 7750–7757. doi:10.1021/ja212012k. PMID 22530571.
10. Huimin Chen; Yang, Jinhu; Cao, Chao; Li, Lin; Su, Qiping; Chen, Bin; Wang, Hangdong; Mao, Qianhui; Xu, Binjie; Du, Jianhua; Minghu Fang (1 April 2016). "Superconductivity in a new layered nickel selenide ${\displaystyle {\ce {CsNi2Se2}}}$". Superconductor Science and Technology. 29 (4): 045008. arXiv:1508.05167. Bibcode:2016SuScT..29d5008C. doi:10.1088/0953-2048/29/4/045008. S2CID 119179572.
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13. Bronger, Welf; Rennau, R. M.; Schmitz, D. (April 1996). "Darstellung und Kristallstruktur von ${\displaystyle {\ce {Rb2Ni3Se4}}}$". Zeitschrift für anorganische und allgemeine Chemie. 622 (4): 627–629. doi:10.1002/zaac.19966220409.
14. Sun, Fan; Guo, Zhongnan; Liu, Ning; Wu, Dan; Lin, Jiawei; Cheng, Erjian; Ying, Tianping; Li, Shiyan; Yuan, Wenxia (16 March 2018). "${\displaystyle {\ce {Cs}}_{0.9}{\ce {Ni}}_{3.1}{\ce {Se3}}}$ : A Ni-Based Quasi-One-Dimensional Conductor with Spin-Glass Behavior". Inorganic Chemistry. 57 (7): 3798–3804. doi:10.1021/acs.inorgchem.7b03143. PMID 29546755.
15. Mellor p444
16. Mellor p445
17. Mellor p446
18. Rommel, Stefan Michael; Krach, Alexander; Peter, Philipp; Weihrich, Richard (25 April 2016). "Conversion Reactions of Solids: From a Surprising Three-Step Mechanism towards Directed Product Formation". Chemistry. 22 (18): 6333–6339. doi:10.1002/chem.201505209. PMID 26997587.
19. Mamedova, N. A.; Ragimov, S. S.; Sadykhov, F. M.; Aliev, I. I. (17 February 2012). "Preparation and physicochemical study of nickel(II) thiostannate in the ${\displaystyle {\ce {NiCl2-SnS2-H2O}}}$ system". Russian Journal of Inorganic Chemistry. 57 (2): 160–162. doi:10.1134/S0036023612020179. S2CID 94801906.
20. Popescu, M. A. (2001-11-30). Non-Crystalline Chalcogenicides. Springer Science & Business Media. p. 73. ISBN 9781402003592.
21. Di Salvo, F.J.; Chen, C.H.; Fleming, R.M.; Waszczak, J.V.; Dunn, R.G.; Sunshine, S.A.; Ibers, James A. (February 1986). "Physical and structural properties of the new layered compounds ${\displaystyle {\ce {Ta2NiS5}}}$ and ${\displaystyle {\ce {Ta2NiSe5}}}$". Journal of the Less Common Metals. 116 (1): 51–61. doi:10.1016/0022-5088(86)90216-X.
22. Tremel, Wolfgang (July 1991). "Isolated and Condensed Ta2Ni2 Clusters in the Layered Tellurides ${\displaystyle {\ce {Ta2Ni2Te4}}}$ and ${\displaystyle {\ce {Ta2Ni3Te5}}}$". Angewandte Chemie International Edition in English. 30 (7): 840–843. doi:10.1002/anie.199108401.