Methyl pivalate

Methyl pivalate

Names
Preferred IUPAC name Methyl 2,2-dimethylpropanoate
Other names Methyl trimethylacetate
Identifiers
CAS Number	598-98-1^Y
3D model (JSmol)	Interactive image
ChemSpider	62249
ECHA InfoCard	100.009.055
EC Number	209-959-1
PubChem CID	69027
UNII	BFX9W386OX^Y
CompTox Dashboard (EPA)	DTXSID4027234
InChI InChI=1S/C6H12O2/c1-6(2,3)5(7)8-4/h1-4H3 Key: CNMFHDIDIMZHKY-UHFFFAOYSA-N
SMILES CC(C)(C)C(=O)OC
Properties
Chemical formula	C6H12O2
Molar mass	116.160 g·mol^−1
Appearance	Colorless liquid
Odor	Vinegar-Like
Density	0.873 g/cm^3
Boiling point	101 °C (214 °F; 374 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Methyl pivalate is an organic compound with the formula CH₃O₂CC(CH₃)₃. It is a colorless liquid, the methyl ester of pivalic acid. The ester is well known for being resistant to hydrolysis to the parent acid. Hydrolysis can be effected with a solution of trimethylsilyl iodide in hot acetonitrile followed by aqueous workup.^{[1] [2]}

References

1. Olah, George A.; Narang, Subhash C.; Gupta, B. G. Balaram; Malhotra, Ripudaman (1979). "Transformations with chlorotrimethylsilane/sodium iodide, a convenient in situ Iodotrimethylsilane Reagent". J. Org. Chem. 44: 1247–1251. doi:10.1021/jo01322a012.
2. "MSDS Methyl trimethylacetate".