Metal-phenolic network

A metal-phenolic network (MPN) is a supramolecular coordination compound that is derived from metal ions and polyphenols that can be deposited onto nearly any surface.[1] [2] MPNs adsorb to a wide variety of surfaces due to noncovalent forces.[3] Possible applications of MPN-based materials include drug delivery, bioimaging, biotechnology, and electrocatalysis.[4][5] For example, they have been commercialized as antimicrobial and anti-odor coatings under the trade name "SWIFF"[6]

References

  1. ^ Hirotaka Ejima; Joseph J. Richardson; Kang Liang; James P. Best; Martin P. van Koeverden; Georgina K. Such; Jiwei Cui; Frank Caruso (2013). "One-Step Assembly of Coordination Complexes for Versatile Film and Particle Engineering". Science. 341 (12): 154–7. Bibcode:2013Sci...341..154E. doi:10.1126/science.1237265. hdl:11343/197428. PMID 23846899. S2CID 26054362.
  2. ^ Guo, Junling; Ping, Yuan; Ejima, Hirotaka; Alt, Karen; Meissner, Mirko; Richardson, Joseph J.; Yan, Yan; Peter, Karlheinz; von Elverfeldt, Dominik; Hagemeyer, Christoph E.; Caruso, Frank (26 May 2014). "Engineering Multifunctional Capsules through the Assembly of Metal-Phenolic Networks". Angewandte Chemie International Edition. 53 (22): 5546–5551. doi:10.1002/anie.201311136. hdl:11343/115252. PMID 24700671.
  3. ^ Ejima, Hirotaka; Richardson, Joseph J.; Caruso, Frank (2017-02-01). "Metal-phenolic networks as a versatile platform to engineer nanomaterials and biointerfaces". Nano Today. 12: 136–148. doi:10.1016/j.nantod.2016.12.012. hdl:11343/127237.
  4. ^ Kim, Nayeong; Lee, Inhui; Choi, Yuri; Ryu, Jungki (2021). "Molecular design of heterogeneous electrocatalysts using tannic acid-derived metal–phenolic networks". Nanoscale. 13 (48): 20374–20386. doi:10.1039/D1NR05901G. ISSN 2040-3364. PMID 34731231. S2CID 239977371.
  5. ^ Guo, Junling; Tardy, Blaise L.; Christofferson, Andrew J.; Dai, Yunlu; Richardson, Joseph J.; Zhu, Wei; Hu, Ming; Ju, Yi; Cui, Jiwei; Dagastine, Raymond R.; Yarovsky, Irene; Caruso, Frank (10 October 2016). "Modular assembly of superstructures from polyphenol-functionalized building blocks". Nature Nanotechnology. 11 (12): 1105–1111. Bibcode:2016NatNa..11.1105G. doi:10.1038/nnano.2016.172. hdl:11343/120178. PMID 27723730.
  6. ^ www.swiffspray.com


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