Odoom, alongside Rickie Haywood-Williams and Charlie Hedges, hosted Kiss Breakfast every weekday morning 6 - 9am, followed by Kiss Morning Anthems until 10am on Kiss 100.[3] Kiss Breakfast won Silver at the Sony Radio Awards in 2009 within the category of "Breakfast Show Award",[3] and was nominated for the same prize in 2010,[4] finally winning 'Gold' at the event in 2012.[5] Odoom was part of the Kiss Breakfast team for 10 years, stepping down in 2018.[6]
In April 2019, the trio moved to BBC Radio 1 to present the late night show Monday – Thursday from 9 to 11pm, also occasionally covering day time shows.[6] In April 2021, It was announced by Radio 1 that Clara Amfo would be moving to evenings on the station to replace Annie Mac. As part of this reshuffle Melvin, Rickie and Charlie would be taking on the 10:30 – 12:45 show including the live lounge.[7]
Television
Odoom and Rickie Haywood-Williams have presented MTV Digs on MTV One, Monday to Saturday between 4 and 7pm and MTV Music Junkie together — a live studio music show.[8] Odoom presented MTV One's coverage of the BRIT Awards 2010 alongside Haywood-Williams,[9] and also presented coverage of the BAFTA awards alongside Kimberly Walsh for MTV One.[9][8]
In 2010, Odoom and Haywood-Williams also presented the backstage online content for Sky1's Must Be the Music.[3]
He is a celebrity ambassador for The Prince's Trust charity, which is involved in helping young adults in life. He is also the brother of actress and writer Yonah Odoom.[12]