Draft:Polyoxide

A polyoxide is a molecule containing 2 or more bound oxygen atoms (R–On–R', n ≥ 2), with the simplest examples found in the group of peroxides, which cont

A polyoxide is a molecule containing 2 or more bound oxygen atoms (R–On–R', n ≥ 2), with the simplest examples found in the group of peroxides, which contain a single O–O bond. Higher polyoxides contain longer oxygen sequences.

Polyoxides can occur in various forms including hydrogen polyoxides (H
2O
n), organic polyoxides (R
2O
n),[1][2] and metal polyoxides (M–O
n). These compounds are of interest in fields such as inorganic chemistry, atmospheric chemistry,[3] astrochemistry,[4] wastewater treatment and materials science.

Chemistry

Polyoxides typically contain consecutive oxygen–oxygen single bonds. These bonds are generally weaker than many other covalent bonds, which makes polyoxides generally reactive or unstable.

See also

References

  1. ^ Gobbato, K. I.; Oberhammer, H.; Klapdor, M. F.; Mootz, D.; Poll, W.; Ulic, S. E.; Willner, H. (1995), "Bis(trifluoromethyl)trioxide: First Structure of a Straight-Chain Trioxide", Angew. Chem. Int. Ed., 34 (20): 2244–2245, doi:10.1002/anie.199522441
  2. ^ Pernice, H.; Berkei, M.; Henkel, G.; Willner, H.; Argüello, G. A.; McKee, M. L.; Webb, T. R. (2004), "Bis(fluoroformyl)trioxide, FC(O)OOOC(O)F", Angew. Chem. Int. Ed., 43 (21): 2843–2846, Bibcode:2004ACIE...43.2843P, doi:10.1002/anie.200353369, PMID 15150764
  3. ^ Berndt, T.; Chen, J.; Kjærgaard, E. R.; Møller, K. H.; Tilgner, A.; Hoffmann, E. H.; Herrmann, H.; Crounse, J. D.; Wennberg, P. O.; Kjaergaard, H. G. (2022), "Hydrotrioxide (ROOOH) formation in the atmosphere", Science, 376 (6596): 979–982, Bibcode:2022Sci...376..979B, doi:10.1126/science.abn6012, PMID 35617402
  4. ^ Bai, X.; Li, C.; Luo, Y.; Gong, Q. A.; Lu, J.; Yang, J.; Pan, Y.; Sun, Z.; Eckhardt, A. K.; Sun, R.; Kaiser, R. I.; Yang, T. (2025), "Formation of hydrogen trioxide (HOOOH) in extraterrestrial ice analogs and its role as an oxidizer in prebiotic chemistry", Sci. Adv., 11 (33) eadw5720, Bibcode:2025SciA...11.5720B, doi:10.1126/sciadv.adw5720, PMC 12356252, PMID 40815663

Category:Polyoxides

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