In polytonic orthography, a rho at the beginning of a word is written with a rough breathing, equivalent to h (ῥrh), and a double rho within a word is written with a smooth breathing over the first rho and a rough breathing over the second (ῤῥrrh). That apparently reflected an aspirated or voiceless pronunciation in Ancient Greek, which led to the various Greek-derived English words starting with rh or containing rrh.
The name of the letter is written in Greek as ῥῶ (polytonic) or ρω/ρο (monotonic).
Other alphabets
Letters that arose from rho include Roman R and Cyrillic Er (Р).
Mathematics and science
The characters ρ and ϱ are also conventionally used outside the Greek alphabetical context in science and mathematics.
Hammett Equation, ρ is used to represent the reaction constant, this is independent of the position and nature of the substituents of the benzene ring.
In economics to represent the discount rate of future pence cash flows
In molecular biology to represent the Rho protein responsible for termination of RNA synthesis. In such occasions, it is often represented as U+03F1ϱGREEK RHO SYMBOL, to avoid confusion with the Latin letter p
These characters are used only as mathematical symbols. Stylized Greek text should be encoded using the normal Greek letters, with markup and formatting to indicate text style:
U+1D6B8𝚸MATHEMATICAL BOLD CAPITAL RHO
U+1D6D2𝛒MATHEMATICAL BOLD SMALL RHO
U+1D6E0𝛠MATHEMATICAL BOLD RHO SYMBOL
U+1D6F2𝛲MATHEMATICAL ITALIC CAPITAL RHO
U+1D70C𝜌MATHEMATICAL ITALIC SMALL RHO
U+1D71A𝜚MATHEMATICAL ITALIC RHO SYMBOL
U+1D72C𝜬MATHEMATICAL BOLD ITALIC CAPITAL RHO
U+1D746𝝆MATHEMATICAL BOLD ITALIC SMALL RHO
U+1D754𝝔MATHEMATICAL BOLD ITALIC RHO SYMBOL
U+1D766𝝦MATHEMATICAL SANS-SERIF BOLD CAPITAL RHO
U+1D780𝞀MATHEMATICAL SANS-SERIF BOLD SMALL RHO
U+1D78E𝞎MATHEMATICAL SANS-SERIF BOLD RHO SYMBOL
U+1D7A0𝞠MATHEMATICAL SANS-SERIF BOLD ITALIC CAPITAL RHO
U+1D7BA𝞺MATHEMATICAL SANS-SERIF BOLD ITALIC SMALL RHO
U+1D7C8𝟈MATHEMATICAL SANS-SERIF BOLD ITALIC RHO SYMBOL