Nitridophosphate

A nitridophosphate is an inorganic compound that contains nitrogen bound to a phosphorus atom, considered as replacing oxygen in a phosphate.

Anions include NPN PN3 P3N6. Related compounds include the oxonitridophosphates[1] imidonitridophosphates,[2] nitridoborophosphates,[3] and nitridosilicatephosphates.[4] By changing the phosphorus, related materials include nitridovanadates and nitridorhenates.[5]

Nitridophosphate compounds include elements from the alkali metals, alkaline earths, first row transition metals, rare earth elements, and some other main group elements.[6]

Characteristics

Nitridophosphate compounds nearly always contain phosphorus in tetrahedral configuration. They can be characterised by the condensation index K which is the ratio of numbers of phosphorus tetrahedral centres to nitrogen vertices. As more nitrogen atoms are shared between phosphorus, condensation increases. The maximum is for P3N5 which no longer has any capacity for cations. For K of 1/2 three dimensional frameworks are produced. For 2/7 or 3/7 layered arrangements of tetrahedra are produced. For 1/3 chains or ring structures are prominent. 1/4 is for uncondensed PN4 compounds. Tow PN4 tetrahedra can also share an edge: P2N6, as the P-N bond is not very polarised, so there is less electrostatic repulsion.[6] Uncondensed compounds are sensitive to air and water but highly condensed compounds are water or acid stable.[6]

Nitridophosphate compounds are usually insulators and are transparent to light.[6]

Formation

Heating P3N5 with a metal nitride at gigapascal pressure and a temperatures of over 1000 °C forms nitridophosphates. P3N5 decomposes over 850°C at ambient pressure. However there are a few nitridophosphates that do no require such high temperatures to form.[7][8]

Heating ammonia under pressure with red phosphorus, and metals, metal nitrides or metal azides is a method called ammonothermal synthesis.[9]

Use

Nitridophosphates are under investigation as luminescent materials, that can covert blue light into red.[8]

List

formula system space group unit cell volume density comment reference
HPN2 tetragonal I42d a = 4.6182 c = 7.0204 Z = 4 [10][11]
HPN3 [12]
β-HP4N7 monoclinic C2/c a = 12.873 b = 4.6587 c = 8.3222 β = 102.351° Z = 4 487.55 3.037 colourless [13]
γ-HP4N7 monoclinic C2/c a=6.82983 b=7.24537 c=8.96504 β = 111.5557° Z = 4 412.604 3.572 high pressure form > 12 GPa; P in trigonal bipyramid [14]
LiPN2 [12]
Li7PN4 cubic P43n a=9.3648 Z=8 tetrahedra [12][15]
β-Li10P4N10 trigonal a=8.71929 c=21.4656 Z=6 1413.3 2.35015 colourless; tetrahedron of 4 tetrahedra [12]
α-Li10P4N10 cubic >80°C [7]
Li5P2N5 monoclinic C2/c a=14.770 b=17.850 c=4.860 β =93.11° layered, high pressure [16]
Li4PN3 orthorhombic Pccn a=9.6597 b=11.8392 c=4.8674 chains [17]
Li12P3N9 monoclinic Cc a=12.094 b=7.649 c=9.711 β=90.53° ring of 3 tetrahedra [12][17]
Li18P6N16 monoclinic P1 a=5.4263 b=7.5354 c=9.8584 α=108.481° β=99.288° γ=104.996° Z=1 355.8 2.496 tricyclic [18]
Li13P4N10Cl3 cubic Fm3m a=13.Z=8 Z=8 2704.27 2.2624 colourless; [7]
Li13P4N10Br3 cubic Fm3m a=14.1096 Z=8 2809.0 2.8088 colourless; [7]
LiP4N7 orthorhombic P212121 a=4.5846 b=8.009 c=13.252 Z=4 485.8 3.130 air stable; grey [19]
Li1.34P6N9.34(NH)1.66 monoclinic P1 a=4.691 b=7.024 c=12.736, α=87.73° β=80.28° γ=70.55° Z=2 390.0 2.988 air stable; grey [19]
BeP2N4 cubic Fd3 a=7.1948 Z=8 372.44 bulk modulus 325 GPa [20]
BP3N6 monoclinic P21/c a=5.027 b=4.5306 c=17.332 β=106.387° Z=4 378.7 3.293 [21]
Li47B3P14N42 trigonal P3c1 a=19.3036 c=18.0200 [22]
NaPN2 [23]
NaP4N7 [19]
Na3P6N11 [19]
Mg2PN3 orthorhombic Cmc21 a=9.723 b=5.6562 c=4.7083 band gap 5.0 eV [12][24]
MgP8N14 orthorhombic a=8.364 b=5.0214 c=23.196 974.3 3.192 [25]
AlP6N11 monoclinic Cm a=4.935 b=8.161 c=9.040 β=98.63° grey; layered; thermal expansion 16.0 ppm/K [26]
Ca2PN3 orthorhombic Cmca a = 5.1914 b =10.3160 c = 11.289 Z = 8 beige; chains [12]
CaP8N14 [25]
Sc5P12N23O3 tetragonal I41/acd a=12.3598 c=24.0151 Z=8 3668.6 3.500 grey [27]
TiP4N8 orthorhombic Pmn21 a=7.6065 b=4.6332 c=7.8601 Z=2 227.01 3.403 [28]
TiP4N8 orthorhombic Pmn21 a=22.9196 b=4.5880 c=8.0970 Z=6 851.44 3.322 [28]
Ti5P12N24O2 tetragonal I41/acd a=a=12.1214 c=23.8458 Z=8 3503.6 3.713 black; Ti3+ & Ti4+ [27]
MnP2N4 hexagonal P6322 a = 16.5543 c = 7.5058 1781.3 [27][29]
FeP8N14 orthorhombic Cmca a=8.2693 = 5.10147 c=23.0776 air stable [30]
CoP8N14 orthorhombic Cmca a=8.25183 b=5.10337 c=22.9675 air stable [30]
NiP8N14 orthorhombic Cmca a=8.23105 b=5.08252 c=22.8516 air stable [30]
CuPN2 tetragonal I42d a = 4.5029 c = 7.6157 154.42 band gap 1.67 eV [23]
Zn2PN3 orthorhombic Cmc21 a = 9.37847 b = 5.47696 c = 4.92396 Z = 4 colourless [31][32]
Zn8P12N24O2 tetragonal I43m a=8.24239 c=8.24239 [33]
Zn8P12N24S2 [33]
Zn8P12N24Se2 [33]
Zn8P12N24Te2 [33]
Zn7P12N24Cl2 sodalite structure [12]
GeP2N4 orthorhombic Pna21 a=9.547 b=7.542 c=4.6941 Z=4 dark grey [34]
Sr3P3N7 monoclinic P2/c a=6.882 b=7.416 c=7.036 β=104.96° Z=2 346.9 4.345 white; decompose in moist air; band gap 4.4 eV [35]
Sr2SiP2N6 orthorhombic C2221 a = 6.0849 b = 8.8203 c = 10.2500 [36]
SrP8N14 [10]
SrP3N5NH monoclinic P21/c a=5.01774 b=8.16912 c=12.70193 β=101.7848° Z=4 [2]
SrH4P6N12 [10]
Sr5Si2P6N16 orthorhombic Pbam a = 9.9136 b = 17.5676 c = 8.3968 [36]
SrAl5P4N10O2F3 tetragonal I4m2 a=11.1685 c=7.8485 Z=2 978.99 3.905 [37]
Sr3P5N10Cl orthorhombic Pnma a=12.240 b=12.953 c=13.427 Z=8 [38]
Sr3P5N10Br orthorhombic Pnma a=12.297 b=12.990 c=13.458 Z=8 [38]
AgPN2 [39]
CdP2N4 hexagonal P6322 a = 16.7197 c = 7.6428 1850.3 [27][29]
InP6N11 grey; layered [26]
BaP2N4 [25]
Ba3P5N10Cl orthorhombic Pnma [38]
Ba3P5N10Br orthorhombic Pnma [38]
BaSr2P6N12 cubic Pa3 a=10.0639 Z=4 1019.3 4.343 [25]
La2P3N7 monoclinic C2/c [35][40]
Ce2P3N7 monoclinic C2/c [35][40]
Ce4Li3P18N35 hexagonal P63/m a=13.9318 c=8.1355 [41]
Pr2P3N7 monoclinic C2/c a = 7.8006 b = 10.2221 c = 7.7798 β = 111.299° Z = 4 [35][40]
Nd2P3N7 P421m [35][40]
LiNdP4N8 orthorhombic Pnma a=8.7305 b=7.8783 c=9.0881 [42]
Sm2P3N7 P421m [35][40]
Eu2P3N7 P421m [35][40]
Ho2P3N7 P421m a = 7.3589 c = 4.9986 Z = 2 [35][40]
Ho3[PN4]O tetragonal I4/mcm a = 6.36112 c = 10.5571 Z = 4 [43]
Yb2P3N7 P421m [35][40]
Hf9−xP24N52−4xO4x (x≈1.84) I41/acd a=12.4443 c=23.7674 Z=4 3680.6 [44]

References

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Stade Mohamed Hamlaoui ملعب محمد حملاوي LocalizaciónPaís  ArgeliaLocalidad Constantina, ArgeliaCoordenadas 36°20′57″N 6°37′33″E / 36.349167, 6.625833Detalles generalesSuperficie Césped naturalCapacidad 40 000[1]​ espectadoresPropietario Ministerio de Deportes y JuventudConstrucciónApertura 5 de julio de 1973Equipo local CS Constantine MO ConstantineAcontecimientos Campeonato Africano de Naciones de 2022[editar datos en Wiki...

 

Pakistan Ordnance Factories

Pakistani State owned weapons manufacturer Pakistan Ordnance FactoriesOfficial logo of Pakistan Ordnance FactoriesNative nameUrdu: پاکستان آرڈیننس فیکٹریاںTypeState-owned companyIndustryFirearms, Defense, MachineryFounded1951; 72 years ago (1951)HeadquartersWah Cantonment, Punjab, PakistanArea servedworldwideKey peopleLt General Syed Tahir Hameed Shah (Chairman)ProductsPistols, Rifles, Submachine gun, Machine gun, Shotguns, Munitions, Explosives, Machin...

Teatro Comunale (Ferrare)

Teatro ComunalePrésentationType Opéra, théâtreFondation XVIIIe siècleArchitectes Antonio Foschini (d), Cosimo Morelli (en)Patrimonialité Bien culturel italien (d)Site web (it) www.teatrocomunaleferrara.itLocalisationLocalisation 44121 Ferrare ItalieCoordonnées 44° 50′ 15″ N, 11° 37′ 13″ Emodifier - modifier le code - modifier Wikidata Le Teatro Comunale (théâtre communal) est l'opéra de Ferrare, principale ville d'Émilie-Romagne. Il...

 

Earl of Rochester

Henry Wilmot, 1. Earl of Rochester Laurence Hyde, 1. Earl of Rochester Earl of Rochester war ein erblicher Adelstitel, der zweimal in der Peerage of England verliehen wurde. Inhaltsverzeichnis 1 Verleihungen und nachgeordnete Titel 2 Liste der Viscounts Wilmot und Earls of Rochester 2.1 Viscounts Wilmot (1621) 2.2 Earls of Rochester, erste Verleihung (1652) 2.3 Earls of Rochester, zweite Verleihung (1682) 3 Siehe auch 4 Weblinks Verleihungen und nachgeordnete Titel Der Titel wurde erstmals am...

 

A Ética Protestante e o Espírito do Capitalismo

Ver artigo principal: Ética Protestante do trabalho Esta página cita fontes, mas que não cobrem todo o conteúdo. Ajude a inserir referências. Conteúdo não verificável pode ser removido.—Encontre fontes: ABW  • CAPES  • Google (N • L • A) (Novembro de 2013) Die protestantische Ethikund der Geist des Kapitalismus A ética protestante e o espírito do capitalismo Capa da edição alemã de 1934 Autor(es) Max Weber Idioma...

Toolbar

Element of computer graphical interfaces Toolbar from MediaWiki OpenOffice.org allows its toolbars to be detached and moved between windows and other toolbars The toolbar, also called a bar or standard toolbar (originally known as ribbon),[1][2] is a graphical control element on which on-screen icons can be used. A toolbar often allows for quick access to functions that are commonly used in the program. Some examples of functions a toolbar might have are open file, save, and c...

 

Rogue Valley Mall

This article needs additional citations for verification. Please help improve this article by adding citations to reliable sources. Unsourced material may be challenged and removed.Find sources: Rogue Valley Mall – news · newspapers · books · scholar · JSTOR (October 2009) (Learn how and when to remove this template message) Shopping mall in Oregon, United StatesRogue Valley MallLocationMedford, Oregon, United StatesCoordinates42°20′36″N 122°52...

 

The Edge of Heaven

This article is about the Wham! song. For the 2 Unlimited song, see Edge of Heaven (2 Unlimited song). For the film by Fatih Akın, see The Edge of Heaven (film). For the TV series, see Edge of Heaven. 1986 single by Wham!The Edge of HeavenSingle by Wham!from the album The Final and Music from the Edge of Heaven B-side Wham Rap '86 (UK) Blue (Live in China) (various) Where Did Your Heart Go? (Japan) Battlestations (various) Released9 June 1986RecordedMarch 1986Genre Dance-pop disco[1]...

Tomcat (2016 film)

2016 film TomcatFilm posterDirected byHändl KlausWritten byHändl KlausProduced byAntonin SvobodaStarringPhilipp HochmairLukas TurturCinematographyGerald KerkletzEdited byJoana ScrinziProductioncompanycoop99 filmproduktionRelease date 13 February 2016 (2016-02-13) (Berlin) Running time119 minutesCountryAustriaLanguageGerman Tomcat (German: Kater) is a 2016 Austrian drama film directed by Klaus Händl.[1] It was shown in the Panorama section at the 66th Berlin Inter...

 

Confederación Federalista Independiente

Confederación Federalista Independiente Líder María Cristina GuzmánFundación 1989Disolución 1991Ideología ConservadurismoFederalismoProvincialismoPosición DerechaCoalición Partido Federal Movimiento Popular Jujeño Partido Renovador de Salta Movimiento Popular Catamarqueño Acción Transformación Partido Línea Popular Partido Acción ChubutensePaís  Argentina[editar datos en Wikidata] La Confederación Federalista Independiente o C.F.I. fue una confederación de par...

 

Hellenic Volleyball Federation

Hellenic Volleyball FederationSportVolleyballJurisdictionGreeceAbbreviationEOΠΕFounded1970 (1970)AffiliationFIVBRegional affiliationCEVPresidentGiorgos KarabetsosOfficial websitewww.volleyball.gr The Hellenic Volleyball Federation (Greek: Ελληνική Ομοσπονδία Πετοσφαίρισης, abbreviated as Ε.Ο.ΠΕ.), is a governing body for volleyball and beach volleyball in Greece. The organization oversees the A1 Ethniki Volleyball league, the Greek Volleyball Cup, the...

يوم الصرائم

هذه مقالة غير مراجعة. ينبغي أن يزال هذا القالب بعد أن يراجعها محرر مغاير للذي أنشأها؛ إذا لزم الأمر فيجب أن توسم المقالة بقوالب الصيانة المناسبة. يمكن أيضاً تقديم طلب لمراجعة المقالة في الصفحة المخصصة لذلك. (أغسطس 2023) يوم الصرائم جزء من تاريخ العرب قبل الإسلام معلومات عامة ا...

 

Containment building

Structure surrounding a nuclear reactor to prevent radioactive releases NRC drawing of the containment building from a pressurized water reactor Reactor Unit 3 (right) and Unit 4 (left) of Fukushima Daiichi on 16 March 2011. Three of the reactors overheated, causing meltdowns which released radioactive material out of their containment structures.[1] A containment building is a reinforced steel, concrete or lead structure enclosing a nuclear reactor. It is designed, in any emergency, ...

 

The Miracle of Life (film)

1926 silent film The Miracle of LifeFilm stillDirected byStanner E.V. TaylorWritten byElizabeth MusgraveOlga PrintzlauStarringPercy MarmontMae BuschNita NaldiCinematographyAlexander G. PenrodProductioncompanyS.E.V. Taylor ProductionsDistributed byAssociated ExhibitorsRelease date February 29, 1926 (1926-02-29) Running time50 minutesCountryUnited StatesLanguageSilent (English intertitles) The Miracle of Life is a 1926 American silent drama film directed by Stanner E.V. Taylor an...

Birch Bay State Park

State park in Washington Birch Bay State ParkLocation in the state of WashingtonLocationWhatcom County, Washington, United StatesNearest cityBlaine, WashingtonCoordinates48°54′11″N 122°45′54″W / 48.90306°N 122.76500°W / 48.90306; -122.76500[1]Area194 acres (79 ha)Elevation33 ft (10 m)[1]DesignationWashington state parkEstablished1954[2]AdministratorWashington State Parks and Recreation CommissionWebsitewww.parks.w...

 

Mitsuki Ichihara

Artikel ini sebatang kara, artinya tidak ada artikel lain yang memiliki pranala balik ke halaman ini.Bantulah menambah pranala ke artikel ini dari artikel yang berhubungan atau coba peralatan pencari pranala.Tag ini diberikan pada April 2017. Mitsuki IchiharaInformasi pribadiNama lengkap Mitsuki IchiharaTanggal lahir 31 Januari 1986 (umur 37)Tempat lahir Prefektur Chiba, JepangPosisi bermain BekKarier senior*Tahun Tim Tampil (Gol)2004-2008 JEF United Chiba * Penampilan dan gol di klub se...

 

Stereocenter

Atom which is the focus of stereoisomerism in a molecule This article has multiple issues. Please help improve it or discuss these issues on the talk page. (Learn how and when to remove these template messages) This article needs additional citations for verification. Please help improve this article by adding citations to reliable sources. Unsourced material may be challenged and removed.Find sources: Stereocenter – news · newspapers · books · scholar ...

Hayes Alan Jenkins

Hayes Alan Jenkins Datos personalesNacimiento Akron (Estados Unidos)23 de marzo de 1933Nacionalidad(es) EstadounidenseCarrera deportivaDeporte Patinaje artístico sobre hielo[editar datos en Wikidata] Hayes Alan Jenkins (Akron, Ohio; 29 de junio de 1933) es un patinador artístico sobre hielo estadounidense retirado, cuatro veces campeón del mundo entre los años 1953 y 1956. Es hermano mayor del también patinador profesional David Jenkins.[1]​ Jenkins además ganó la compe...

 

Ryder (novel)

Ryder Cover of first edition of the novel Ryder (1928) by Djuna BarnesAuthorDjuna BarnesLanguageEnglishGenreModernist NovelPublisherBoni & LiverightPublication date1928Media typePrint (hardcover, paperback) Ryder (1928) is the first novel by Djuna Barnes. A composite of different literary styles, from lyrical poetry to sentimental fiction, it is an example of a modernist novel in the Rabelaisian tradition of bawdy and parodic fiction. Nearly every chapter is written in a different st...

 

Strategi Solo vs Squad di Free Fire: Cara Menang Mudah!