The sole archer for the Central African Republic competing in the 2000 Summer Olympics was Henriette Youanga, in the women's individual. She took part in the two ranking rounds on 16 September at the Sydney International Archery Park. She scored 238 and 252 in the ranking rounds; placing 63rd out of the 64 competitors in each round, as well as overall. These rounds were used to allocate archers against each other in the single elimination tournament. Based on the result, Youanga was drawn against Natalia Valeeva of Italy, who had finished second overall in the ranking rounds.[5] The match between the two took place the following day, with Valeeva winning by 166 points to Youanga's 126.[6]
The Central African Republic was represented by two athletes in athletics; Mickaël Conjungo in the men's discus throw and Maria-Joëlle Conjungo in the women's 100 metres hurdles. Mickaël Conjungo, competing in his third Olympic Games, threw a foul in his first throw in the discus, but recorded a distance of 57.85 metres (189.8 ft) with his second throw. His third throw was shorter, at 55.60 metres (182.4 ft), so his second throw was counted as the longest for the round. This mean he finished in sixteenth place, ending his appearances at the Games since only the first 12 competitors qualified for the following round.[7][8]
Maria-Joëlle Conjungo took part in the 100 metres on 25 September in the second heat. She finished in seventh place with a time of 13.95 seconds; the top six qualified for the following round, four automatically and then those in fifth and sixth place due to finishing among the four fastest runners up overall.[9]