Catena scored his first professional goal on 21 October 2018, netting the equalizer in a 2–1 home defeat of CF Rayo Majadahonda. The following January, he terminated his contract with the Catalans due to the club's poor financial situation overall.[5]
On 16 January 2020, after establishing himself as a starter, Catena renewed with Rayo until 2023.[7] He scored three goals in 46 appearances overall during the 2020–21 campaign, as the club returned to the top tier.
Catena scored his first goal in the main category of Spanish football on 18 December 2021, netting his team's second in a 2–0 home win over Deportivo Alavés.
Osasuna
On 9 June 2023, fellow first division side CA Osasuna reached an agreement with Catena for a five-year contract, at the conclusion of his Rayo deal.[8] Prior to making a competitive appearance for his new side, he scored a hat-trick against local rivals Real Sociedad (all from headers) in the pre-season Euskal Herriko Txapela match.[9]